Unusual Ring Opening of Bicyclic Terpenes During Pd-Catalyzed Coupling with Aromatic Halides Научная публикация
| Журнал |
Advanced Syntethys and Catalysis
ISSN: 1615-4150 |
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| Вых. Данные | Год: 2023, Номер: 365, Страницы: 4256– 4 Страниц : DOI: 10.1002/adsc.202300594 | ||||||
| Ключевые слова | Cross-coupling; bicyclic terpene; Heck reaction; palladium catalyst; ring openin | ||||||
| Авторы |
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Реферат:
Herein we describe Pd-catalyzed cross-coupling reaction of α-pinene derivative – pinacarvone O-methyl oxime (1) with aryl halides (2). Surprisingly, the formation of the C−C coupling product was accompanied by an unexpected opening of the pinene bicyclic structure. The (Z)-2-aryl-4,4,5-trimethylcyclohexa-2,5-dien-1-one O-methyl oxime (3) was formed as the resulting product. The reaction conditions of the developed synthetic procedure were carefully optimized and the reaction mechanism was supposed on the basis of data obtained by structural and computational methods.
Библиографическая ссылка:
Shutovskaya E.S.
, Ustimenko Y.P.
, Tkachev A.V.
, Burykina J.V.
, Agafontsev A.M.
, Lastovka A.V.
, Polovyanenko D.N.
, Sukhikh T.S.
Unusual Ring Opening of Bicyclic Terpenes During Pd-Catalyzed Coupling with Aromatic Halides
Advanced Syntethys and Catalysis. 2023. №365. С.4256– 4. DOI: 10.1002/adsc.202300594 WOS Scopus РИНЦ OpenAlex
Unusual Ring Opening of Bicyclic Terpenes During Pd-Catalyzed Coupling with Aromatic Halides
Advanced Syntethys and Catalysis. 2023. №365. С.4256– 4. DOI: 10.1002/adsc.202300594 WOS Scopus РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 5 июн. 2023 г. |
| Опубликована online: | 14 нояб. 2023 г. |
| Опубликована в печати: | 30 нояб. 2023 г. |
Идентификаторы БД:
| Web of science: | WOS:001101827500001 |
| Scopus: | 2-s2.0-85176320395 |
| РИНЦ: | 64400386 |
| OpenAlex: | W4388044734 |