Sciact
  • EN
  • RU

X-ray emission and X-ray photoelectron study of the electronic structure of paramagnetic and diamagnetic derivatives of 3-imidazoline Full article

Journal Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779
Output data Year: 2014, Volume: 55, Number: 6, Pages: 1044-1056 Pages count : 13 DOI: 10.1134/S0022476614060079
Tags free nitroxyl radicals; 3-imidazoline derivatives; X-ray photoelectron spectroscopy; X-ray emission spectroscopy; effective charges; spin density
Authors Mazalov L.N. 1,4 , Fedorenko A.D. 1 , Kryuchkova N.A. 1,4 , Dikov Yu.P. 2 , Polienko Yu.F. 3 , Grigor'ev I.A. 3
Affiliations
1 (Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
2 (Данные Web of science) Russian Acad Sci, Inst Geol Ore Deposits Petrog Mineral & Geochem, Moscow, Russia
3 (Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia
4 (Данные Web of science) Novosibirsk State Univ, Novosibirsk, Russia

Abstract: X-ray emission spectra of oxygen OK (alpha) and X-ray photoelectron O1s spectra are obtained for stable nitroxyl radicals: 3-imidazoline derivatives and their diamagnetic derivatives. It is shown that the highest occupied molecular orbitals in the nitroxyl radicals mainly consist of oxygen and nitrogen 2p atomic orbitals of the nitroxyl group. Distinctions in the X-ray emission spectra of oxygen of the compounds studied can be due to the presence of the unpaired electron in the radicals.
Cite: Mazalov L.N. , Fedorenko A.D. , Kryuchkova N.A. , Dikov Y.P. , Polienko Y.F. , Grigor'ev I.A.
X-ray emission and X-ray photoelectron study of the electronic structure of paramagnetic and diamagnetic derivatives of 3-imidazoline
Journal of Structural Chemistry. 2014. V.55. N6. P.1044-1056. DOI: 10.1134/S0022476614060079 WOS Scopus РИНЦ OpenAlex
Original: Мазалов Л.Н. , Федоренко А.Д. , Крючкова Н.А. , Диков Ю.П. , Полиенко Ю.Ф. , Григорьев И.А.
Рентгеноспектральное и рентгеноэлектронное изучение электронного строения парамагнитных и диамагнитных производных 3-имидазолина
Журнал структурной химии (J STRUCT CHEM+). 2014. Т.55. №6. С.1100-1113. РИНЦ
Dates:
Published print: Nov 1, 2014
Published online: Jan 24, 2015
Identifiers:
Web of science: WOS:000348401200007
Scopus: 2-s2.0-84921677506
Elibrary: 24030359
OpenAlex: W2081102757
Citing:
DB Citing
Web of science 2
Scopus 2
Elibrary 2
OpenAlex 3
Altmetrics: