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Synthesis of 5,5-Disubstituted N-Methyl-1,3-oxazinanes Containing Monoterpene Fragments Full article

Journal Doklady Chemistry
ISSN: 0012-5008
Output data Year: 2023, Volume: 512 part 2, Pages: 281-287 Pages count : 7 DOI: 10.1134/S001250082360058X
Tags oxazine, tetrahydro-1,3-oxazine, oxazinane, aminopropanol, propanolamine, pinene, Knoevenagel condensation, alkylation of cyanoacetic ester, ethyl cyanoacetate
Authors Nechepurenko I.V. 1 , Volcho K.P. 1 , Salakhutdinov N.F. 1
Affiliations
1 Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Abstract: A new method has been developed for the synthesis of 5,5-disubstituted N-methyl-1,3-oxazinanes as a mixture of diastereomers at the 5-position containing monoterpene and branched alkyl substituents in the 5-position. 1,3-Oxazinanes were obtained for the first time by reacting 2,2-substituted 3-aminopropan-1-ols with formaldehyde and sodium borohydride in one stage.
Cite: Nechepurenko I.V. , Volcho K.P. , Salakhutdinov N.F.
Synthesis of 5,5-Disubstituted N-Methyl-1,3-oxazinanes Containing Monoterpene Fragments
Doklady Chemistry. 2023. V.512 part 2. P.281-287. DOI: 10.1134/S001250082360058X WOS РИНЦ OpenAlex
Original: Нечепуренко И.В. , Волчо К.П. , Салахутдинов Н.Ф.
СИНТЕЗ 5,5-ДИЗАМЕЩЕННЫХ N-МЕТИЛ-1,3-ОКСАЗИНАНОВ, СОДЕРЖАЩИХ МОНОТЕРПЕНОВЫЕ ФРАГМЕНТЫ
Доклады Российской академии наук. Химия, науки о материалах.. 2023. Т.512. С.75-82. DOI: 10.31857/S2686953522600283 РИНЦ OpenAlex
Dates:
Submitted: Jun 9, 2022
Accepted: Nov 21, 2022
Identifiers:
Web of science: WOS:001130184300001
Elibrary: 65019761
OpenAlex: W4390191029
Citing: Пока нет цитирований
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