Synthesis and Single‐Electron Oxidation of Bulky Bis(m‐terphenyl)chalcogenides: The Quest for Kinetically Stabilized Radical Cations

Synthesis and Single‐Electron Oxidation of Bulky Bis(m‐terphenyl)chalcogenides: The Quest for Kinetically Stabilized Radical Cations Full article

Journal

Chemistry - A European Journal
ISSN: 0947-6539 , E-ISSN: 1521-3765

Output data

Year: 2023, Volume: 29, Number: 11, Article number : e202203498, Pages count : DOI: 10.1002/chem.202203498

Authors

Duvinage Daniel ¹ , Mostaghimi Farzin ¹ , Damrath Mattis ¹ , Spils Julian ¹ , Komorr Pascal ¹ , Odintsov Danila S. ² , Fedin Matvey ³ , Shundrin Leonid A. ² , Mebs Stefan ⁴ , Beckmann Jens ¹

Affiliations

1	Institutfür Anorganische Chemieund Kristallographie Universität Bremen
2	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch of Russian Academy of Sciences
3	International Tomography Center SB RAS
4	Institutfür Experimentalphysik Freie Universität Berlin 14195Berlin(Germany)

Funding (1)

Российский Научный Фонд

22-13-00108

Stericallyencumberedbis(m-terphenyl)chalco-genides,(2,6-Mes2C6H3)2E (E=S, Se, Te) wereobtainedby thereactionof thechalcogentetrafluorides,EF4, withthreeequivalentsofm-terphenyllithium,2,6-Mes2C6H3Li. Thesingle-electronoxidationof (2,6-Mes2C6H3)2Te usingXeF2/K[B(C6F5)4] affordedtheradicalcation[(2,6-Mes2C6H3)2Te][B-(C6F5)4] thatwasisolatedandfullycharacterized.Theelectro-chemicaloxidationof the lighterhomologs(2,6-Mes2C6H3)2E(E=S, Se) wasirreversibleandimpairedby rapiddecom-position

Duvinage D. , Mostaghimi F. , Damrath M. , Spils J. , Komorr P. , Odintsov D.S. , Fedin M. , Shundrin L.A. , Mebs S. , Beckmann J.
Synthesis and Single‐Electron Oxidation of Bulky Bis(m‐terphenyl)chalcogenides: The Quest for Kinetically Stabilized Radical Cations
Chemistry - A European Journal. 2023. V.29. N11. e202203498 . DOI: 10.1002/chem.202203498 WOS Scopus РИНЦ OpenAlex

Published online:	Nov 23, 2022
Published print:	Feb 21, 2023

Web of science:	WOS:000911182300001
Scopus:	2-s2.0-85146012546
Elibrary:	60164240
OpenAlex:	W4309748355

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