Synthesis of silver nanoparticles stabilized by carboxylated methoxypolyethylene glycols: the role of carboxyl terminal groups in the particle size and morphology

Synthesis of silver nanoparticles stabilized by carboxylated methoxypolyethylene glycols: the role of carboxyl terminal groups in the particle size and morphology Full article

Journal

Journal of Inclusion Phenomena and Macrocyclic Chemistry
ISSN: 0923-0750 , E-ISSN: 1573-1111

Output data

Year: 2019, Volume: 94, Number: 3-4, Pages: 287-295 Pages count : 9 DOI: 10.1007/s10847-019-00921-x

Tags

Silver; Nanoparticles; Polyethylene glycol; Surface modification

Authors

Titkov Alexander, I ¹ , Logutenko Olga A. ¹ , Gerasimov Evgeny Yu ² , Shundrina Inna K. ³ , Karpova Elena, V ³ , Lyakhov Nikolay Z. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Inst Solid State Chem & Mechanochem, Kutateladze 18, Novosibirsk 630128, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Pr Acad Lavrentieva 5, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Prospekt Akad Lavrentieva 9, Novosibirsk 630090, Russia

In this work the effect of the synthesis conditions on the size and morphology of the nanoparticles obtained via the reduction of silver ions by benzyl alcohol in the presence of carboxylated methoxypolyethylene glycols with different molecular weights (mPEG-COOH 350, containing a terminal carboxyl group, M(W)350 and 2-[2-(2-methoxyethoxy)ethoxy]acetic acid (MEEAA), M(W)200) and non-carboxylated mPEG 350 has been studied. The synthesized nanoparticles were characterized by means of X-ray diffraction (XRD), high-resolution transmission electron microscopy (HR-TEM), Ultraviolet-Visible (UV-Vis) and Fourier-transform infrared (FT-IR) spectroscopy. The synthesis conditions resulting in the formation of silver nanoparticles stabilized by MEEAA and mPEG-COOH with the average sizes of 6.5 +/- 1.1 and 5.2 +/- 0.9nm, respectively, which can be used for the fabrication of ink compositions for flexible electronics, were found. A thermogravimetric (TG) study showed that MEEAA and mPEG-COOH are removed from the surface of the silver nanoparticles at temperatures of 110-300 and 200-310 degrees C, respectively. Thus, according to the TG data, the particles stabilized by MEEAA can potentially be used in the fabrication of inks for printing on low-temperature polymer substrates. The as-synthesized nanoparticles form a stable dispersion and therefore are suitable for possible applications in printed electronics.

Titkov A.I. , Logutenko O.A. , Gerasimov E.Y. , Shundrina I.K. , Karpova E.V. , Lyakhov N.Z.
Synthesis of silver nanoparticles stabilized by carboxylated methoxypolyethylene glycols: the role of carboxyl terminal groups in the particle size and morphology
Journal of Inclusion Phenomena and Macrocyclic Chemistry. 2019. V.94. N3-4. P.287-295. DOI: 10.1007/s10847-019-00921-x WOS Scopus РИНЦ OpenAlex

Published online:	May 23, 2019
Published print:	Aug 1, 2019

Web of science:	WOS:000473623100020
Scopus:	2-s2.0-85068765926
Elibrary:	41642420
OpenAlex:	W2946764300

DB	Citing
Web of science	16
Scopus	14
Elibrary	16
OpenAlex	19