Isokinetic relationships for SNAr reactions in different solvents Full article
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Journal of Physical Organic Chemistry
ISSN: 0894-3230 |
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| Output data | Year: 2013, Volume: 26, Number: 2, Pages: 131-136 Pages count : DOI: 10.1002/poc.2954 | ||
| Tags | activation parameters; isokinetic relationship; isokinetic temperature; reaction mechanism; SNAr reactions; substituent effects; transition state | ||
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Abstract:
On the basis of the changes of the activation parameters d Hint and d S and the statistically significant isokinetic and compensation temperatures, Tiso and Tcomp, for the SNAr reactions of the benzene derivatives with anionic and neutral nucleophiles at their structural variations in different solvents, the general isokinetic relationship d?Hint? versus (Tiso - Tcomp). d S was found. The existence of this isokinetic relationship for a series of SNAr reactions suggests the possibility to predict the Tiso value or to interpret it when it is experimentally determined. Copyright (C) 2012 John Wiley & Sons, Ltd.
Cite:
Vlasov V.M.
, Kornakova T.A.
Isokinetic relationships for SNAr reactions in different solvents
Journal of Physical Organic Chemistry. 2013. V.26. N2. P.131-136. DOI: 10.1002/poc.2954 WOS Scopus РИНЦ OpenAlex
Isokinetic relationships for SNAr reactions in different solvents
Journal of Physical Organic Chemistry. 2013. V.26. N2. P.131-136. DOI: 10.1002/poc.2954 WOS Scopus РИНЦ OpenAlex
Dates:
| Published online: | Apr 27, 2012 |
| Published print: | Feb 1, 2013 |
Identifiers:
| Web of science: | WOS:000314071700011 |
| Scopus: | 2-s2.0-84872896792 |
| Elibrary: | 23965652 |
| OpenAlex: | W2258824625 |