Sciact
  • EN
  • RU

Solid-Phase Reactions of Humic Acids with Sodium Percarbonate as a Way to Study Processes Occurring on the Mechanochemical Oxidation of Brown Coal Full article

Journal Solid Fuel Chemistry
ISSN: 0361-5219 , E-ISSN: 1934-8029
Output data Year: 2023, Volume: 57, Number: 6, Pages: 402-410 Pages count : 9 DOI: 10.3103/s0361521923060071
Tags humic acids, brown coal, mechanochemistry, solid-phase oxidation
Authors Skripkina T.S. 1 , Yudina L.I. 1,2 , Tikhova V.D. 3 , Bychkov A.L. 1 , Lomovsky I.O. 1
Affiliations
1 Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 600090 Russia
2 Novosibirsk National Research State University, Novosibirsk, 600090 Russia
3 Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 600090 Russia

Abstract: The reactions of humic acids in a pure form and in the composition of coal with sodium percarbonate occurring on solid-phase mechanochemical treatment were compared. Analysis for CHNO, IR spectroscopy, and potentiometric titration were used to study changes in the composition of humic acids mechanochemically treated after isolation from brown coal. The sorption properties in relation to heavy metal ions (Zn2+, Cu2+, and Cd2+) and their changes as a result of the treatment were studied. The results were correlated with data similar to those for humic acids in coal that underwent mechanochemical treatment. It was demonstrated that, at present, an increase in the yield of humic acids and the concentrations of phenolic and carboxyl groups in brown coal as a result of treatment with sodium percarbonate can be explained by the oxidation of fractions other than humic acids in the organic matter of brown coal.
Cite: Skripkina T.S. , Yudina L.I. , Tikhova V.D. , Bychkov A.L. , Lomovsky I.O.
Solid-Phase Reactions of Humic Acids with Sodium Percarbonate as a Way to Study Processes Occurring on the Mechanochemical Oxidation of Brown Coal
Solid Fuel Chemistry. 2023. V.57. N6. P.402-410. DOI: 10.3103/s0361521923060071 WOS Scopus РИНЦ OpenAlex
Original: Скрипкина Т.С. , Юдина Л.И. , Тихова В.Д. , Бычков А.Л. , Ломовский И.О.
Исследование результатов твердофазной реакции гуминовых кислот с перкарбонатом натрия как способ изучения процессов, происходящих при механохимическом окислении бурого угля
Химия твердого топлива. 2023. №6. С.40-48. DOI: 10.31857/S0023117723060087 РИНЦ OpenAlex
Dates:
Submitted: Jun 15, 2023
Accepted: Jul 19, 2023
Published online: Nov 24, 2023
Identifiers:
Web of science: WOS:001117661500004
Scopus: 2-s2.0-85178262225
Elibrary: 55927634
OpenAlex: W4388973092
Citing:
DB Citing
OpenAlex 2
Scopus 2
Web of science 2
Elibrary 2
Altmetrics: