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Transformations of several monoterpenoids in the presence of aldehydes in supercritical solvents Full article

Journal Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X
Output data Year: 2013, Volume: 87, Number: 3, Pages: 382-387 Pages count : DOI: 10.1134/S0036024413030023
Tags supercritical solvent; terpenoids; verbenol epoxide; isopulegol; aldehydes; alumina
Authors Anikeev V. I. 1 , Sivcev V. P. 2 , Il'ina I. V. 3 , Korchagina D. V. 3 , Statsenko O. B. 3 , Volcho K. P. 3 , Salakhutdinov N. F. 3
Affiliations
1 (Данные Web of science) Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk, Russia
2 (Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3 (Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia

Abstract: The reactivity of verbenol epoxide and isopulegol in supercritical solvents in the presence of aromatic aldehydes was studied using a flow type reactor and a heterogeneous catalyst (Al2O3) or no catalyst. The intramolecular transformations or interactions of reagents with the solvent prevailed in all cases; the yield of the products of intermolecular reactions of terpenoids with aldehydes was up to 1%. The aldehydes did not interact with verbenol epoxide but produced a considerable effect on the distribution of its isomerization products.
Cite: Anikeev V.I. , Sivcev V.P. , Il'ina I.V. , Korchagina D.V. , Statsenko O.B. , Volcho K.P. , Salakhutdinov N.F.
Transformations of several monoterpenoids in the presence of aldehydes in supercritical solvents
Russian Journal of Physical Chemistry A. 2013. V.87. N3. P.382-387. DOI: 10.1134/S0036024413030023 WOS Scopus РИНЦ OpenAlex
Dates:
Published online: Feb 3, 2013
Published print: Mar 1, 2013
Identifiers:
Web of science: WOS:000314407800008
Scopus: 2-s2.0-84879657264
Elibrary: 20437382
OpenAlex: W2074440730
Citing:
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Web of science 5
Scopus 5
Elibrary 5
OpenAlex 5
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