Synthesis, Structure and Emission Properties of [Cu-2(mu(2)-I)(2)L-4] Complex Based on 2-(Methylthio)Pyrazine Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2019, Volume: 60, Number: 6, Pages: 967-971 Pages count : 5 DOI: 10.1134/S0022476619060118 | ||||||
| Tags | copper(I); pyrazines; sulfide ligands; photoluminescence; crystal structure | ||||||
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Abstract:
Reaction of 2-(methylthio)pyrazine (L) with CuI (MeCN, r.t.) results in formation of iodide-bridged complex [Cu-2(mu(2)-I)(2)L-4], wherein CuCu contact of 2.6351(4) angstrom is observed. The each metal atom of the [Cu-2(mu(2)-I)(2)] core is coordinated by the two ligands via 4-pyrazyl nitrogen atoms. In the solid state at room temperature, the complex obtained emits an orange photoluminescence (lambda(max) = 600 nm) with the average lifetime of 1.66 mu s and quantum yield of 17%.
Cite:
Artem'ev A.V.
, Beresin A.S.
, Bagryanskaya I.Y.
Synthesis, Structure and Emission Properties of [Cu-2(mu(2)-I)(2)L-4] Complex Based on 2-(Methylthio)Pyrazine
Journal of Structural Chemistry. 2019. V.60. N6. P.967-971. DOI: 10.1134/S0022476619060118 WOS Scopus РИНЦ OpenAlex
Synthesis, Structure and Emission Properties of [Cu-2(mu(2)-I)(2)L-4] Complex Based on 2-(Methylthio)Pyrazine
Journal of Structural Chemistry. 2019. V.60. N6. P.967-971. DOI: 10.1134/S0022476619060118 WOS Scopus РИНЦ OpenAlex
Original:
Artem'ev A.V.
, Berezin A.S.
, Bagryanskaya I.Y.
SYNTHESIS, STRUCTURE AND EMISSION PROPERTIES OF [CU2(M2-I)2L4] COMPLEX BASED ON 2-(METHYLTHIO)PYRAZINE
Журнал структурной химии (J STRUCT CHEM+). 2019. V.60. N6. P.1008-1012. DOI: 10.26902/JSC_id40732 РИНЦ OpenAlex
SYNTHESIS, STRUCTURE AND EMISSION PROPERTIES OF [CU2(M2-I)2L4] COMPLEX BASED ON 2-(METHYLTHIO)PYRAZINE
Журнал структурной химии (J STRUCT CHEM+). 2019. V.60. N6. P.1008-1012. DOI: 10.26902/JSC_id40732 РИНЦ OpenAlex
Dates:
| Published print: | Jun 1, 2019 |
| Published online: | Jul 4, 2019 |
Identifiers:
| Web of science: | WOS:000474373600011 |
| Scopus: | 2-s2.0-85068769287 |
| Elibrary: | 41642596 |
| OpenAlex: | W2953512452 |