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Design of Postmetallocene Catalytic Systems of Arylimine Type for Olefin Polymerization: XIX. Synthesis of N-(4-Allyloxy-2,3,5,6-tetrafluorophenyl)salicylaldimines and Their Complexes with Titanium(IV) Dichloride Full article

Journal Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350
Output data Year: 2022, Volume: 92, Number: 8, Pages: 1457-1466 Pages count : 10 DOI: 10.1134/s1070363222080138
Tags salicylic aldehydes 4-allyloxy-2,3,5,6-tetrafluoroaniline salicylaldarylimines titanium(IV) dichloride complexes
Authors Oleynik I.V. 1 , Oleynik I.I. 1
Affiliations
1 N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences

Abstract: The reaction of 3- and 3,5-substituted salicylic aldehydes containing tert-butyl or 2-phenylpropan-2-yl groups in position 3 with 4-allyloxy-2,3,5,6-tetrafluoroaniline in toluene in the presence of para-toluenesulfonic acid was used to obtain a series of corresponding (N-aryl)salicylaldimines, which form complexes of titanium(IV) dichloride L2TiCl2 upon interaction with TiCl2(OPr-i)2.
Cite: Oleynik I.V. , Oleynik I.I.
Design of Postmetallocene Catalytic Systems of Arylimine Type for Olefin Polymerization: XIX. Synthesis of N-(4-Allyloxy-2,3,5,6-tetrafluorophenyl)salicylaldimines and Their Complexes with Titanium(IV) Dichloride
Russian Journal of General Chemistry. 2022. V.92. N8. P.1457-1466. DOI: 10.1134/s1070363222080138 WOS РИНЦ OpenAlex
Original: Олейник И.В. , Олейник И.И.
Дизайн постметаллоценовых каталитических систем арилиминного типа для полимеризации олефинов:XIX.1 синтез n-(4-аллилокси-2,3,5,6-тетрафторфенил)салицилальдиминов и их комплексов с дихлоридом титана(IV)
Журнал общей химии (RUSS J GEN CHEM+). 2022. Т.92. №8. С.1263-1274. DOI: 10.31857/S0044460X22080133 РИНЦ OpenAlex
Dates:
Submitted: May 5, 2022
Accepted: Jun 13, 2022
Published online: Sep 15, 2022
Identifiers:
Web of science: WOS:000854784000013
Elibrary: 53705717
OpenAlex: W4295955456
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