2-Methyl-11-nitro-5,6-dihydro-2H-2,6-methano-1,3,5-benzoxadiazocin-4(3H)-one: synthesis, crystal structure and tautomerism in dipolar aprotic solvents Full article
| Journal |
Mendeleev Communications
ISSN: 0959-9436 |
||
|---|---|---|---|
| Output data | Year: 2013, Volume: 23, Number: 3, Pages: 176-178 Pages count : DOI: 10.1016/j.mencom.2013.05.020 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
Condensation of salicylaldehyde with nitroacetone and urea yields one diastereomer of the title compound. In DMF or DMSO solutions, this compound undergoes oxadiazocine ring opening leading to the equilibrium between its 2R*, 6S*, 11S*- and 2R*, 6S*,11R*-diastereomers and 4-(2-hydroxyphenyl)-6-methyl-5-nitro-3,4-dihydropyrimidin-2(1H)-one.
Cite:
Sedova V.F.
, Krivopalov V.P.
, Gatilov Y.V.
, Shkurko O.P.
2-Methyl-11-nitro-5,6-dihydro-2H-2,6-methano-1,3,5-benzoxadiazocin-4(3H)-one: synthesis, crystal structure and tautomerism in dipolar aprotic solvents
Mendeleev Communications. 2013. V.23. N3. P.176-178. DOI: 10.1016/j.mencom.2013.05.020 WOS Scopus РИНЦ OpenAlex
2-Methyl-11-nitro-5,6-dihydro-2H-2,6-methano-1,3,5-benzoxadiazocin-4(3H)-one: synthesis, crystal structure and tautomerism in dipolar aprotic solvents
Mendeleev Communications. 2013. V.23. N3. P.176-178. DOI: 10.1016/j.mencom.2013.05.020 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | May 1, 2013 |
Identifiers:
| Web of science: | WOS:000321540500020 |
| Scopus: | 2-s2.0-84879096098 |
| Elibrary: | 20436238 |
| OpenAlex: | W2952676182 |