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Skeletal transformations of pentafluorophenylation products of perfluorinated 1,2-dialkyl-1,2-dihydrocyclobutabenzenes in SbF5 Full article

Journal Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393
Output data Year: 2013, Volume: 49, Number: 10, Pages: 1454-1465 Pages count : 12 DOI: 10.1134/S1070428013100096
Authors Mezhenkova T.V. 1 , Sinyakov V.R. 1 , Karpov V.M. 1 , Platonov V.E. 1
Affiliations
1 (Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Abstract: Perfluorinated 1-ethyl-2-methyl- and 1-isopropyl-2-methyl-1,2-dihydrocyclobutabenzenes reacted with pentafluorobenzene in SbF5 to generate perfluoro(1-ethyl-2-methyl-2-phenyl- and perfluoro(1-izopropyl-2-methyl-2-phenyl-1,2-dihydrocyclobutabenzen-1-yl) cations. These cations in SbF5 at 20A degrees C underwent opening of the four-membered ring and its expansion to five-membered. After hydrolysis, perfluorinated 4-[1-(2-propylphenyl)ethylidene]- and 4-[1-(2-isobutylphenyl)ethylidene]-2,5-cyclohexadien-1-ones were obtained together with perfluoro(3-ethyl- and perfluoro(3-isopropyl-2-phenylinden-1-ones).
Cite: Mezhenkova T.V. , Sinyakov V.R. , Karpov V.M. , Platonov V.E.
Skeletal transformations of pentafluorophenylation products of perfluorinated 1,2-dialkyl-1,2-dihydrocyclobutabenzenes in SbF5
Russian Journal of Organic Chemistry. 2013. V.49. N10. P.1454-1465. DOI: 10.1134/S1070428013100096 WOS Scopus РИНЦ OpenAlex
Original: Меженкова Т.В. , Синяков В.Р. , Карпов В.М. , Платонов В.Е.
Скелетные превращения продуктов пентафторфенилирования перфтор-1,2-диалкилбензоциклобутенов в sbf 5
Журнал органической химии (RUSS J ORG CHEM+). 2013. Т.49. №10. С.1476-1487. РИНЦ
Dates:
Published print: Oct 1, 2013
Published online: Nov 8, 2013
Identifiers:
Web of science: WOS:000326813100009
Scopus: 2-s2.0-84889027078
Elibrary: 21896967
OpenAlex: W1980299742
Citing:
DB Citing
Web of science 6
Scopus 5
Elibrary 5
OpenAlex 6
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