Synthesis, structure, and luminescence of the octahedral molybdenum cluster [Mo6I8(SC6F4H)(6)](2-)

Synthesis, structure, and luminescence of the octahedral molybdenum cluster [Mo6I8(SC6F4H)(6)](2-) Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2013, Volume: 62, Number: 8, Pages: 1764-1767 Pages count : 4 DOI: 10.1007/s11172-013-0253-4

Tags

molybdenum iodides; clusters; organofluorine compounds; thiolate complexes; luminescence

Authors

Sokolov M.N. ^1,2 , Mikhailov M.A. ¹ , Virovets A.V. ¹ , Brylev K.A. ^1,2 , Bredikhin R.A. ³ , Maksimov A.M. ³ , Platonov V.E. ³ , Fedin V.P. ^1,2

Affiliations

1	(Данные Web of science) Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

A new thiolate cluster complex (Bu4N)(2)[Mo6I8(SC6F4H)(6)] was synthesized by the metathesis reaction of (Bu4N)(2)[Mo6I14] and HC6F4SAg in methylene chloride. According to the X-ray structure determination, the cluster core {Mo6I8}(4+) coordinates six thiolate ligands 2,3,5,6-HC6F4S-. The Mo-Mo and Mo-I distances have their usual values. The average Mo-S distance is 2.538(4) , and the Mo-S-C angles range from 107 to 109A degrees. Compound (Bu4N)(2)[Mo6I8(SC6F4H)(6)] both in solid and in solution displays a bright red microsecond luminescence, which is typical of octahedral molybdenum halide complexes.

Sokolov M.N. , Mikhailov M.A. , Virovets A.V. , Brylev K.A. , Bredikhin R.A. , Maksimov A.M. , Platonov V.E. , Fedin V.P.
Synthesis, structure, and luminescence of the octahedral molybdenum cluster [Mo6I8(SC6F4H)(6)](2-)
Russian Chemical Bulletin. 2013. V.62. N8. P.1764-1767. DOI: 10.1007/s11172-013-0253-4 WOS Scopus РИНЦ OpenAlex

Соколов М.Н. , Михайлов М.А. , Вировец А.В. , Брылев К.А. , Бредихин Р.А. , Максимов А.М. , Платонов В.Е. , Федин В.П.
Синтез, строение и люминесцентные свойства октаэдрического кластерного комплекса молибдена [mo 6i 8(sc 6f 4h) 6] 2-
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 2013. №8. С.1754. РИНЦ

Published print:	Aug 1, 2013
Published online:	Apr 25, 2014

Web of science:	WOS:000335331400008
Scopus:	2-s2.0-84902978452
Elibrary:	23976242
OpenAlex:	W2039903281

DB	Citing
Web of science	22
Scopus	21
OpenAlex	23