Turning on the triplet state channel in the excess electron scavenging by nitroxyl radicals in liquid alkanes Научная публикация
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Chemical Physics Letters
ISSN: 0009-2614 , E-ISSN: 1873-4448 |
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| Вых. Данные | Год: 2012, Том: 531, Страницы: 86-89 Страниц : DOI: 10.1016/j.cplett.2012.02.011 | ||||||
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Реферат:
It has been found that the effective radius of the reaction of excess electrons capture by 4-phenyl-2,2,3,5,5-pentamethyl-imidazolidin-1-oxyl in n-dodecane, n-decane, and n-hexane increases steeply by a factor of about four, reaching values typical for molecular acceptors, when the temperature is reduced below 290, 280, and 250, respectively. A kinetic model of the capture that is based on the assumption of equilibrium between electron detachment and intersystem crossing in the triplet state of the diradical anion is suggested and briefly discussed. (C) 2012 Elsevier B.V. All rights reserved.
Библиографическая ссылка:
Borovkov V.I.
, Ivanishko I.S.
, Beregovaya I.V.
, Reznikov V.A.
Turning on the triplet state channel in the excess electron scavenging by nitroxyl radicals in liquid alkanes
Chemical Physics Letters. 2012. V.531. P.86-89. DOI: 10.1016/j.cplett.2012.02.011 WOS Scopus РИНЦ OpenAlex
Turning on the triplet state channel in the excess electron scavenging by nitroxyl radicals in liquid alkanes
Chemical Physics Letters. 2012. V.531. P.86-89. DOI: 10.1016/j.cplett.2012.02.011 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 апр. 2012 г. |
Идентификаторы БД:
| Web of science: | WOS:000301931800016 |
| Scopus: | 2-s2.0-84858750547 |
| РИНЦ: | 17980839 |
| OpenAlex: | W2015668453 |