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REACTION OF SEVERAL RESVERATROL GLYCOSIDE DERIVATIVES WITH HYPOCHLORITES IN VARIOUS MEDIA Full article

Journal Chemistry of Natural Compounds
ISSN: 0009-3130 , E-ISSN: 1573-8388
Output data Year: 2012, Volume: 48, Number: 1, Pages: 1-7 Pages count : DOI: 10.1007/s10600-012-0146-z
Tags resveratrol; stilbene glycosides; oxidation; hypochlorites; triphenylmethyl ethers; TEMPO
Authors Rogachev A. D. 1 , Komarova N. I. 1 , Pozdeeva A. V. 2 , Korchagina D. V. 1 , Vasil'ev V. G. 1 , Salakhutdinov N. F. 1 , Tolstikov G. A. 1
Affiliations
1 (Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

Abstract: The reactions of pterostilbenoside (trans-3,5-dimethoxystilben-4'-O-beta-D-glucoside) and Ar-O-Tr derivatives of resveratroloside (3,5-dihydroxystilben-4'-O-beta-D-glucoside) and pinostilbenoside (3-methoxy-5-hydroxystilben-4'-O-beta-D-glucoside) with NaOCl and t-BuOCl in the presence of the stable nitroxyl radical TEMPO were studied in various media. It was found that the principal product of pterostilbenoside transformation was its 2,6-dichloroderivative, a part of which was oxidized to form 2,6-dichloropterostilbene glucuronide. Trityl ethers of resveratroloside and pinostilbenoside reacted with the hypochlorites to form mixtures of products.
Cite: Rogachev A.D. , Komarova N.I. , Pozdeeva A.V. , Korchagina D.V. , Vasil'ev V.G. , Salakhutdinov N.F. , Tolstikov G.A.
REACTION OF SEVERAL RESVERATROL GLYCOSIDE DERIVATIVES WITH HYPOCHLORITES IN VARIOUS MEDIA
Chemistry of Natural Compounds. 2012. V.48. N1. P.1-7. DOI: 10.1007/s10600-012-0146-z WOS Scopus РИНЦ OpenAlex
Dates:
Published print: Mar 1, 2012
Published online: Mar 21, 2012
Identifiers:
Web of science: WOS:000302243100001
Scopus: 2-s2.0-84858318611
Elibrary: 17980325
OpenAlex: W2077024478
Citing:
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Web of science 1
Scopus 1
Elibrary 2
OpenAlex 7
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