Copper(II) and copper(I) tetrafluoroborate complexes with 4-(3,5-diphenyl-1H-pyrazol-1-yl)-6-(piperidin-1-yl)pyrimidine (L): Synthesis, structures and luminescence

Copper(II) and copper(I) tetrafluoroborate complexes with 4-(3,5-diphenyl-1H-pyrazol-1-yl)-6-(piperidin-1-yl)pyrimidine (L): Synthesis, structures and luminescence Full article

Journal

Inorganica Chimica Acta
ISSN: 0020-1693 , E-ISSN: 1873-3255

Output data

Year: 2012, Volume: 386, Pages: 116-121 Pages count : DOI: 10.1016/j.ica.2012.02.004

Tags

Copper(II); Copper(I); Pyrazolylpyrimidines; N-ligands; Weakly coordinated anions; Luminescence

Authors

Vinogradova Katerina A. ¹ , Krivopalov Viktor P. ² , Nikolaenkova Elena B. ² , Pervukhina Natalia V. ¹ , Naumov Dmitrii Yu. ¹ , Sheludyakova Lilia A. ^1,3 , Bushuev Mark B. ^1,3

Affiliations

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk State Univ, Natl Res Univ, Dept Nat Sci, Novosibirsk 630090, Russia

Copper(II) and copper(I) complexes, [(CuL2)-L-II(BF4)(2)]center dot 0.5H(2)O, [CuIL2](BF4)center dot 2MeCN and [CuIL2](BF4)center dot H2O, with 4-(3,5-diphenyl-1H-pyrazol-1-yl)-6-(piperidin-1-yl)pyrimidine (L) have been synthesized. The compound [(CuL2)-L-II(BF4)(2)]center dot 0.5H(2)O was obtained in the M:L = 1: 1 and 1: 2 molar ratios in EtOH solutions. It represents an example of a complex containing coordinated BF4 anion. The Cu-F(BF3) distances, 1.964(2) and 2.000(2) angstrom, are the shortest for copper tetrafluoroborate complexes. The compounds [(CuL2)-L-I](BF4)center dot 2MeCN and [(CuL2)-L-I](BF4)center dot H2O were obtained in the M:L = 1: 1 and 1: 2 molar ratios in MeCN solutions. According to X-ray data, the molecules of L in the structures of [(CuL2)-L-II(BF4)(2)]center dot 0.5H(2)O and [(CuL2)-L-I](BF4)center dot 2MeCN are coordinated to the copper atoms through N-2(pyrazole) and N-3(pyrimidine) atoms. The complex [(CuL2)-L-I](BF4)center dot 2MeCN is unstable in the ambient air and transforms into [(CuL2)-L-I(BF4)]center dot H2O. The complex [(CuL2)-L-I](BF4)center dot H2O was found to display orange photoluminescence. (C) 2012 Elsevier B. V. All rights reserved.

Vinogradova K.A. , Krivopalov V.P. , Nikolaenkova E.B. , Pervukhina N.V. , Naumov D.Y. , Sheludyakova L.A. , Bushuev M.B.
Copper(II) and copper(I) tetrafluoroborate complexes with 4-(3,5-diphenyl-1H-pyrazol-1-yl)-6-(piperidin-1-yl)pyrimidine (L): Synthesis, structures and luminescence
Inorganica Chimica Acta. 2012. V.386. P.116-121. DOI: 10.1016/j.ica.2012.02.004 WOS Scopus РИНЦ OpenAlex

Published print:

May 1, 2012

Web of science:	WOS:000302808700018
Scopus:	2-s2.0-84858309069
Elibrary:	17980161
OpenAlex:	W2020685457

DB	Citing
Web of science	17
Scopus	13
Elibrary	13
OpenAlex	19