Hydrodefluorination of polyfluoro-2-naphthylamines by Zn in aqueous NH3: A correlation of the product distribution and the computationally predicted regioselectivity of the substrate radical anion fragmentation Full article
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Output data | Year: 2012, Volume: 137, Pages: 64-72 Pages count : DOI: 10.1016/j.jfluchem.2012.02.012 | ||||
| Tags | Polyfluoro-2-naphthylamines; Hydrodefluorination; CVA measurements; Quantum-chemical calculations; X-ray analysis | ||||
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Abstract:
Hydrodefluorination of heptafluoro-2-naphthylamine and its less fluorinated analogues by zinc in aqueous ammonia has been explored with respect to the possibility to occur and to rationalize the product distribution in terms of the mechanism including formation and fragmentation of a polyfluoroarene radical anion. (c) 2012 Published by Elsevier B.V.
Cite:
Selivanova G.A.
, Reshetov A.V.
, Beregovaya I.V.
, Vasil'eva N.V.
, Bagryanskaya I.Y.
, Shteingarts V.D.
Hydrodefluorination of polyfluoro-2-naphthylamines by Zn in aqueous NH3: A correlation of the product distribution and the computationally predicted regioselectivity of the substrate radical anion fragmentation
Journal of Fluorine Chemistry. 2012. V.137. P.64-72. DOI: 10.1016/j.jfluchem.2012.02.012 WOS Scopus РИНЦ OpenAlex
Hydrodefluorination of polyfluoro-2-naphthylamines by Zn in aqueous NH3: A correlation of the product distribution and the computationally predicted regioselectivity of the substrate radical anion fragmentation
Journal of Fluorine Chemistry. 2012. V.137. P.64-72. DOI: 10.1016/j.jfluchem.2012.02.012 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | May 1, 2012 |
Identifiers:
| Web of science: | WOS:000304179700008 |
| Scopus: | 2-s2.0-84859562826 |
| Elibrary: | 17982256 |
| OpenAlex: | W2062338252 |