Activation parameters of transesterification of 4-nitrophenyl acetate in the presence of K2CO3 in DMF Full article
| Journal |
Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
||
|---|---|---|---|
| Output data | Year: 2012, Volume: 48, Number: 9, Pages: 1197-1199 Pages count : 3 DOI: 10.1134/S1070428012090084 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
The activation parameters for the reactions of 4-nitrophenyl acetate with 4-chlorophenol and benzenethiol in the presence of potassium carbonate in dimethylformamide were determined. Depending on the substrate structure, the enthalpy and entropy of activation decrease in going from 4-nitrophenyl acetate to 4-nitrophenyl benzoate, while the Gibbs energy of activation increases.
Cite:
Os'kina I.A.
Activation parameters of transesterification of 4-nitrophenyl acetate in the presence of K2CO3 in DMF
Russian Journal of Organic Chemistry. 2012. V.48. N9. P.1197-1199. DOI: 10.1134/S1070428012090084 WOS Scopus РИНЦ OpenAlex
Activation parameters of transesterification of 4-nitrophenyl acetate in the presence of K2CO3 in DMF
Russian Journal of Organic Chemistry. 2012. V.48. N9. P.1197-1199. DOI: 10.1134/S1070428012090084 WOS Scopus РИНЦ OpenAlex
Original:
Оськина И.А.
Активационные параметры переэтерификации 4-нитрофенилацетата в присутствии k2co3 в дмфа
Журнал органической химии (RUSS J ORG CHEM+). 2012. Т.48. №9. С.1198-1200. РИНЦ
Активационные параметры переэтерификации 4-нитрофенилацетата в присутствии k2co3 в дмфа
Журнал органической химии (RUSS J ORG CHEM+). 2012. Т.48. №9. С.1198-1200. РИНЦ
Dates:
| Published print: | Sep 1, 2012 |
| Published online: | Oct 10, 2012 |
Identifiers:
| Web of science: | WOS:000309724000008 |
| Scopus: | 2-s2.0-84868600360 |
| Elibrary: | 20489725 |
| OpenAlex: | W1978028261 |