Synthetic transformations of sesquiterpene lactones 6.(star) Alantolactone and isoalantolactone derivatives in the Heck reaction Full article
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Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 2012, Volume: 61, Number: 10, Pages: 1975-1985 Pages count : DOI: 10.1007/s11172-012-0274-4 | ||
| Tags | alantolactone; isoalantolactone; epoxyisoalantolactone; alloalantolactone; Heck reaction | ||
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Abstract:
The Heck reaction of the eudesman-type methylidenelactones (alantolactone, alloalanto- lactone, and 4,15-epoxyisoalantolactone) with haloarenes afforded the corresponding (E)-13-aryleudesma-4(15), 11(13)-dien-8 beta,12-olides and 11-arylmethyl-13-noreudesma-4(15), 7(11)-dien-8 alpha,12-olides. The yields and the ratios of the arylation products depended on the reaction conditions and the structure of lactone. Certain side processes were found to take place.
Cite:
Shul'ts E.E.
, Belovodskii A.V.
, Shakirov M.M.
, Tolstikov G.A.
Synthetic transformations of sesquiterpene lactones 6.(star) Alantolactone and isoalantolactone derivatives in the Heck reaction
Russian Chemical Bulletin. 2012. V.61. N10. P.1975-1985. DOI: 10.1007/s11172-012-0274-4 WOS Scopus РИНЦ OpenAlex
Synthetic transformations of sesquiterpene lactones 6.(star) Alantolactone and isoalantolactone derivatives in the Heck reaction
Russian Chemical Bulletin. 2012. V.61. N10. P.1975-1985. DOI: 10.1007/s11172-012-0274-4 WOS Scopus РИНЦ OpenAlex
Original:
Шульц Э.Э.
, Беловодский А.В.
, Шакиров М.М.
, Толстиков Г.А.
Синтетические трансформации сесквитерпеновых лактонов. сообщение 6. производные алантолактона и изоалантолактона в реакции Хека
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 2012. №10. С.1959-1968. РИНЦ
Синтетические трансформации сесквитерпеновых лактонов. сообщение 6. производные алантолактона и изоалантолактона в реакции Хека
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 2012. №10. С.1959-1968. РИНЦ
Dates:
| Published print: | Oct 1, 2012 |
| Published online: | Jul 14, 2013 |
Identifiers:
| Web of science: | WOS:000322778800019 |
| Scopus: | 2-s2.0-84887450962 |
| Elibrary: | 21897408 |
| OpenAlex: | W2124372310 |