Formation of fluorene and anthracene derivatives in reactions of perfluorinated 1-alkyl-1-phenyl- and 1-alkyl-2-phenyl-1,2-dihydrocylobutabenzenes with antimony pentafluoride Full article
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Output data | Year: 2011, Volume: 47, Number: 7, Pages: 1018-1025 Pages count : DOI: 10.1134/S1070428011070098 | ||
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Abstract:
The reaction of perfluoro(1-methyl-1-phenyl-1,2-dihydrocyclobutabenzene) with SbF(5) at 50A degrees C, followed by hydrolysis, gave perfluoro(1-phenylindan-1-ol), while analogous reaction at 90A degrees C afforded perfluoro[10-methylanthracen-9(10H)-one]. Perfluoro(1-methyl-2-phenyl-1,2-dihydrocyclobutabenzene) did not undergo skeletal transformations under analogous conditions, whereas at 200A degrees C it was converted mainly into perfluoro(9-methylfluoren-9-ol). Perfluoro(1-ethyl-2-phenyl-1,2-dihydrocyclobutabenzene) reacted with SbF5 at 200A degrees C to form perfluoro(9-ethylfluoren-9-ol) together with perfluorinated 9,9-dimethyl- and 9-ethyl-9-methyl-1,2,3,4-tetrahydro-9H-fluorenes.
Cite:
Mezhenkova T.V.
, Karpov V.M.
, Platonov V.E.
Formation of fluorene and anthracene derivatives in reactions of perfluorinated 1-alkyl-1-phenyl- and 1-alkyl-2-phenyl-1,2-dihydrocylobutabenzenes with antimony pentafluoride
Russian Journal of Organic Chemistry. 2011. V.47. N7. P.1018-1025. DOI: 10.1134/S1070428011070098 WOS Scopus РИНЦ OpenAlex
Formation of fluorene and anthracene derivatives in reactions of perfluorinated 1-alkyl-1-phenyl- and 1-alkyl-2-phenyl-1,2-dihydrocylobutabenzenes with antimony pentafluoride
Russian Journal of Organic Chemistry. 2011. V.47. N7. P.1018-1025. DOI: 10.1134/S1070428011070098 WOS Scopus РИНЦ OpenAlex
Original:
Меженкова Т.В.
, Карпов В.М.
, Платонов В.Е.
Образование производных флуорена и антрацена в реакциях перфторированных 1,1- и 1,2-алкилфенил- бензоциклобутенов с пятифтористой сурьмой
Журнал органической химии (RUSS J ORG CHEM+). 2011. Т.47. №7. С.1004-1011. РИНЦ
Образование производных флуорена и антрацена в реакциях перфторированных 1,1- и 1,2-алкилфенил- бензоциклобутенов с пятифтористой сурьмой
Журнал органической химии (RUSS J ORG CHEM+). 2011. Т.47. №7. С.1004-1011. РИНЦ
Dates:
| Published print: | Jul 1, 2011 |
| Published online: | Aug 6, 2011 |
Identifiers:
| Web of science: | WOS:000293643600009 |
| Scopus: | 2-s2.0-80052410185 |
| Elibrary: | 18003606 |
| OpenAlex: | W2002538810 |