Synthesis, Structure, Magnetic and Photoluminescent Properties of Lanthanide(III) Complexes with a Ligand Based on 1,10-Phenanthroline and (+)-3-Carene

Synthesis, Structure, Magnetic and Photoluminescent Properties of Lanthanide(III) Complexes with a Ligand Based on 1,10-Phenanthroline and (+)-3-Carene Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2019, Volume: 60, Number: 8, Pages: 1314-1326 Pages count : 13 DOI: 10.1134/S0022476619080110

Tags

lanthanides; complexes; terpenes; (+)-3-carene; structure; magnetic properties; photoluminescence

Authors

Bryleva Yu A. ^1,4 , Glinskaya L.A. ¹ , Agafontsev A.M. ^2,4 , Rakhmanova M., I ¹ , Bogomyakov A.S. ^3,4 , Sukhikh T.S. ^1,4 , Gorbunova E.A. ^1,4 , Tkachev A., V ^2,4 , Larionov S., V ^1,4

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia
3	(Данные Web of science) Russian Acad Sci, Int Tomog Ctr, Siberian Branch, Novosibirsk, Russia
4	(Данные Web of science) Novosibirsk State Univ, Novosibirsk, Russia

Ionic complexes of the composition [LnL(2)(NO3)(2)](2)[Ln(NO3)(5)]3Me(2)CO (Ln = Sm (1), Eu (2), Tb (3), Dy (4)) with an optically active ligand L containing 1,10-phenanthroline and (+)-3-carene moieties are synthesized. According to the X-ray crystallographic data, the crystal structure of compound 2 is composed of complex [EuL2(NO3)(2)](+) cations (N6O4 polyhedron) and complex [Eu(NO3)(5)](2-) anions (O-10 polyhedron), and also Me2CO molecules. The L and NO3 ligands perform both tridentate and bidentate chelating functions respectively. Complexes 1-4 are isostructural and crystallize in the non-centrosymmetric space group P1; their magnetic properties are studied in the temperature range 2-300 K. The mu(eff) values for 1-4 at 300 K are 3.14 mu(B), 6.08 mu(B), 16.76 mu(B), and 18.30 mu(B) respectively and are typical of Ln(3+) ions. For complex 3 significant anisotropy results in a nonlinear field dependence of the magnetization at 2 K. Complexes 1-4 exhibit metal-centered orange (Sm3+), red (Eu3+), green (Tb3+), and yellow (Dy3+) luminescence in the solid state at room temperature. Luminescence quantum yield decreases for solid samples in the order 2 > 1 > 3 approximate to 4.

Bryleva Y.A. , Glinskaya L.A. , Agafontsev A.M. , Rakhmanova M.,.I. , Bogomyakov A.S. , Sukhikh T.S. , Gorbunova E.A. , Tkachev A.,.V. , Larionov S.,.V.
Synthesis, Structure, Magnetic and Photoluminescent Properties of Lanthanide(III) Complexes with a Ligand Based on 1,10-Phenanthroline and (+)-3-Carene
Journal of Structural Chemistry. 2019. V.60. N8. P.1314-1326. DOI: 10.1134/S0022476619080110 WOS Scopus РИНЦ OpenAlex

Брылева Ю.А. , Глинская Л.А. , Агафонцев А.М. , Рахманова М.И. , Богомяков А.С. , Сухих Т.С. , Горбунова Е.А. , Ткачев А.В. , Ларионов С.В.
Синтез, структура, магнитные и фотолюминесцентные свойства комплексов лантанидов(III) с лигандом на основе 1,10-фенантролина и (+)-3-карена
Журнал структурной химии (J STRUCT CHEM+). 2019. Т.60. №8. С.1366-1378. DOI: 10.26902/JSC_id44174 РИНЦ OpenAlex

Published print:	Aug 1, 2019
Published online:	Sep 4, 2019

Web of science:	WOS:000486152800011
Scopus:	2-s2.0-85071778901
Elibrary:	41679550
OpenAlex:	W2971427577

DB	Citing
Web of science	6
Scopus	4
Elibrary	4
OpenAlex	7