Degenerate rearrangement of long-lived 9-cyclopropyl-9,10-dimethyl-9,10-dihydrophenanthren-9-ylium: Migration of cyclopropyl group Научная публикация
| Журнал |
Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Вых. Данные | Год: 2010, Том: 46, Номер: 3, Страницы: 311-317 Страниц : 7 DOI: 10.1134/S1070428010030012 | ||
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Реферат:
Dynamic NMR study showed that long-lived 9-cyclopropyl-9,10-dimethyl-9,10-dihydrophenanthren-9-yl cation generated from 9-cyclopropyl-9,10-dimethyl-9,10-dihydrophenanthren-9-ol in HSO(3)F-SO(2)ClF-CD(2)Cl(2) at -100 to -75A degrees C undergoes fast degenerate 1,2-shift of the cyclopropyl group. The Arrhenius parameters for this process were determined: E (a) = 33.7 kJ/mol, log A = 13.0.
Библиографическая ссылка:
Genaev A.M.
, Sal'nikov G.E.
, Shubin V.G.
Degenerate rearrangement of long-lived 9-cyclopropyl-9,10-dimethyl-9,10-dihydrophenanthren-9-ylium: Migration of cyclopropyl group
Russian Journal of Organic Chemistry. 2010. V.46. N3. P.311-317. DOI: 10.1134/S1070428010030012 WOS Scopus РИНЦ OpenAlex
Degenerate rearrangement of long-lived 9-cyclopropyl-9,10-dimethyl-9,10-dihydrophenanthren-9-ylium: Migration of cyclopropyl group
Russian Journal of Organic Chemistry. 2010. V.46. N3. P.311-317. DOI: 10.1134/S1070428010030012 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 мар. 2010 г. |
| Опубликована online: | 24 апр. 2010 г. |
Идентификаторы БД:
| Web of science: | WOS:000277012800001 |
| Scopus: | 2-s2.0-77952487821 |
| РИНЦ: | 15313791 |
| OpenAlex: | W2164934908 |