Synthesis of solvates of the copper(II) complex with chiral caryophyllane-type morpholino oxime (HL). Structure of Cu(HL)Cl-2 center dot CHCl3 Full article
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284 |
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| Output data | Year: 2010, Volume: 36, Number: 8, Pages: 579-584 Pages count : 6 DOI: 10.1134/S107032841008004X | ||||
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Abstract:
Paramagnetic Cu(HL)Cl-2 center dot 0.25CHCl(3) (I) and Cu(HL)C1(2) center dot 0.25CH(2)C1(2) (II), where HL is the optically active morpholino oxime obtained from the terpenoid caryophyllene, were synthesized. The crystals of Cu(HL)Cl-2 center dot CHCl3 (III) were isolated. According to X-ray diffraction data, the crystals of III are composed of acentric mononuclear complex molecules Cu(HL)Cl-2 and solvate molecules CHCl3. In the complex molecules, the Cu ion coordinates two N atoms of the bidentate chelating ligand HL and two C1 atoms at the vertices of a distorted tetrahedron. The translationally identical molecules of the complex combined by H-bonds form chains along the axis x.
Cite:
Larionov S.V.
, Myachina L.I.
, Glinskaya L.A.
, Klevtsova R.F.
, Boguslavskii E.G.
, Agafontsev A.M.
, Tkachev A.V.
Synthesis of solvates of the copper(II) complex with chiral caryophyllane-type morpholino oxime (HL). Structure of Cu(HL)Cl-2 center dot CHCl3
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2010. V.36. N8. P.579-584. DOI: 10.1134/S107032841008004X WOS Scopus РИНЦ OpenAlex
Synthesis of solvates of the copper(II) complex with chiral caryophyllane-type morpholino oxime (HL). Structure of Cu(HL)Cl-2 center dot CHCl3
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2010. V.36. N8. P.579-584. DOI: 10.1134/S107032841008004X WOS Scopus РИНЦ OpenAlex
Original:
Ларионов С.В.
, Мячина Л.И.
, Глинская Л.А.
, Клевцова Р.Ф.
, Богуславский Е.Г.
, Агафонцев А.М.
, Ткачев А.В.
Синтез сольватов комплекса меди(II) с хиральным морфолинооксимом кариoфилланового типа (HL). структура соединения Cu(HL)Cl2 · CHCl3
Координационная химия (RUSS J COORD CHEM+). 2010. Т.36. №8. С.583-588. РИНЦ
Синтез сольватов комплекса меди(II) с хиральным морфолинооксимом кариoфилланового типа (HL). структура соединения Cu(HL)Cl2 · CHCl3
Координационная химия (RUSS J COORD CHEM+). 2010. Т.36. №8. С.583-588. РИНЦ
Dates:
| Published print: | Aug 1, 2010 |
| Published online: | Aug 17, 2010 |
Identifiers:
| Web of science: | WOS:000281014200004 |
| Scopus: | 2-s2.0-78449274704 |
| Elibrary: | 16671630 |
| OpenAlex: | W2000121257 |