High-spin complex [FeL2(NCS)(2)]center dot H2O [L=3,5-di(pyrimidin-2-yl)-4H-1,2,4-triazol-4-amine]: Synthesis and properties

High-spin complex [FeL2(NCS)(2)]center dot H2O [L=3,5-di(pyrimidin-2-yl)-4H-1,2,4-triazol-4-amine]: Synthesis and properties Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2010, Volume: 80, Number: 8, Pages: 1703-1709 Pages count : DOI: 10.1134/S1070363210080220

Authors

Bushuev M. B. ^1,2 , Krivopalov V. P. ³ , Daletskii V. A. ¹ , Varnek V. A. ¹ , Sheludyakova L. A. ^1,2 , Yushina I. V. ¹ , Shkurko O. P. ³

Affiliations

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia

Complex [FeL2(NCS)(2)]center dot H2O (L = 3,5-di(pyrimidin-2-yl)-4H-1,2,4-triazol-4-amine) was prepared as the first example of complex compounds of transition metals with 3,5-di(pyrimidin-2-yl)-4H-1,2,4-triazol-4-amines. The coordination core of the iron atom is a distorted octahedron FeN6. In the range 80-300 K the complex is high-spin, mu(eff) similar to 5.3 MB. The parameter of the crystal field splitting, 10Dq, for [FeL2(NCS)(2)]center dot H2O is similar to 10800 cm(-1).

Bushuev M.B. , Krivopalov V.P. , Daletskii V.A. , Varnek V.A. , Sheludyakova L.A. , Yushina I.V. , Shkurko O.P.
High-spin complex [FeL2(NCS)(2)]center dot H2O [L=3,5-di(pyrimidin-2-yl)-4H-1,2,4-triazol-4-amine]: Synthesis and properties
Russian Journal of General Chemistry. 2010. V.80. N8. P.1703-1709. DOI: 10.1134/S1070363210080220 WOS Scopus РИНЦ OpenAlex

Published print:	Aug 1, 2010
Published online:	Sep 22, 2010

Web of science:	WOS:000282090800022
Scopus:	2-s2.0-78149434329
Elibrary:	16715775
OpenAlex:	W2018836397

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