Chiral complexes of PdCl2 with hydroxypyrazolylquinoline and pyrazolylquinoline based on the monoterpenoid (+)-3-carene: Synthesis and structures Научная публикация
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284 |
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| Вых. Данные | Год: 2010, Том: 36, Номер: 9, Страницы: 685-692 Страниц : 8 DOI: 10.1134/S1070328410090083 | ||||
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Реферат:
The chiral complexes [(PdLCl2)-Cl-1] (I) and [(PdLCl2)-Cl-2] (II) (where L-1 and L-2 are hydroxypyrazolylquinoline and pyrazolylquinoline, respectively, based on the monoterpenoid (+)-3-carene) were obtained and examined using X-ray diffraction. The crystal structures of complexes I and II are built from mononuclear acentric molecules. The Pd2+ ions coordinate two N atoms of the chelating bidentate ligand L-1 or L-2 and two Cl atoms. The coordination polyhedron Cl2N2 is a square distorted in a tetrahedral manner. In structure I, adjacent molecules are linked by intermolecular contacts and hydrogen bonds Cl center dot center dot center dot H-O, which gives rise to chains aligned with the axis x. In structure II, contacts that are substantially shorter than the van der Waals interactions were not detected.
Библиографическая ссылка:
Savel'eva Z.A.
, Klevtsova R.F.
, Glinskaya L.A.
, Popov S.A.
, Tkachev A.V.
, Larionov S.V.
Chiral complexes of PdCl2 with hydroxypyrazolylquinoline and pyrazolylquinoline based on the monoterpenoid (+)-3-carene: Synthesis and structures
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2010. V.36. N9. P.685-692. DOI: 10.1134/S1070328410090083 WOS Scopus РИНЦ OpenAlex
Chiral complexes of PdCl2 with hydroxypyrazolylquinoline and pyrazolylquinoline based on the monoterpenoid (+)-3-carene: Synthesis and structures
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2010. V.36. N9. P.685-692. DOI: 10.1134/S1070328410090083 WOS Scopus РИНЦ OpenAlex
Оригинальная:
Савельева З.А.
, Клевцова Р.Ф.
, Глинская Л.А.
, Попов С.А.
, Ткачев А.В.
, Ларионов С.В.
Синтез и структура хиральных комплексов PdCl2 с пиразолинолхинолином и пиразолилхинолином, построенными на основе монотерпеноида (+)-3-карена
Координационная химия (RUSS J COORD CHEM+). 2010. Т.36. №9. С.691-698. РИНЦ
Синтез и структура хиральных комплексов PdCl2 с пиразолинолхинолином и пиразолилхинолином, построенными на основе монотерпеноида (+)-3-карена
Координационная химия (RUSS J COORD CHEM+). 2010. Т.36. №9. С.691-698. РИНЦ
Даты:
| Опубликована в печати: | 1 сент. 2010 г. |
| Опубликована online: | 22 сент. 2010 г. |
Идентификаторы БД:
| Web of science: | WOS:000282091800008 |
| Scopus: | 2-s2.0-78049377484 |
| РИНЦ: | 16671270 |
| OpenAlex: | W1976377888 |