Complex of Cu-II with a chiral Schiff base (H2L) derived from the natural monoterpene (+)-6h-pinene. Synthesis and the properties of the complex and its solvate with acetonitrile. Crystal structure of [Cu(HL)Cl]aEuro cent H2O

Complex of Cu-II with a chiral Schiff base (H2L) derived from the natural monoterpene (+)-6h-pinene. Synthesis and the properties of the complex and its solvate with acetonitrile. Crystal structure of [Cu(HL)Cl]aEuro cent H2O Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2010, Volume: 59, Number: 4, Pages: 712-716 Pages count : DOI: 10.1007/s11172-010-0151-y

Tags

synthesis; copper(II) complexes; chiral Schiff bases; (+)-alpha-pinene; X-ray diffraction analysis

Authors

Kokina T. E. ¹ , Klevtsova R. F. ¹ , Glinskaya L. A. ¹ , Boguslavskii E. G. ¹ , Koneva E. A. ² , Volcho K. P. ² , Larionov S. V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

A reaction of CuCl2 with a chiral Schiff base (H2L) derived from (+)-6h-pinene leads to paramagnetic complex Cu(HL)Cl (1) (fu(eff) = 2.03 fuB) and solvate Cu(HL)ClaEuro cent MeCN (2) (fueff = 1.87 fuB). Monocrystals of hydrate [Cu(HL)Cl]aEuro cent H2O (3) were grown for the X-ray diffraction study, which showed that the crystal structure of 3 consists of the molecules of a mononuclear complex [Cu(HL)Cl] containing tridentate chelating ligand HL-, and water molecules. Coordination polyhedron ClNO2 is a distorted tetrahedron. Intermolecular con- tacts in the structure 3 lead to the formation of supramolecular chains, parallel to the axis -6h. Compounds 1 and 2 were studied by ESR and IR spectroscopy.

Kokina T.E. , Klevtsova R.F. , Glinskaya L.A. , Boguslavskii E.G. , Koneva E.A. , Volcho K.P. , Larionov S.V.
Complex of Cu-II with a chiral Schiff base (H2L) derived from the natural monoterpene (+)-6h-pinene. Synthesis and the properties of the complex and its solvate with acetonitrile. Crystal structure of [Cu(HL)Cl]aEuro cent H2O
Russian Chemical Bulletin. 2010. V.59. N4. P.712-716. DOI: 10.1007/s11172-010-0151-y WOS Scopus РИНЦ OpenAlex

Кокина Т.Е. , Клевцова Р.Ф. , Глинская Л.А. , Богуславский Е.Г. , Конева Е.А. , Волчо К.П. , Ларионов С.В.
Синтез и свойства комплекса Cu II с хиральным основанием шиффа (H 2L) на основе природного монотерпена (+)-α-пинена и его сольвата с ацетонитрилом. кристаллическая структура [Cu(Cl)Cl]•H2O
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 2010. №4. С.698. РИНЦ

Published print:	Apr 1, 2010
Published online:	Oct 21, 2010

Web of science:	WOS:000283302000007
Scopus:	2-s2.0-77958604948
Elibrary:	16716116
OpenAlex:	W1963754889

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