Supramolecular 1D assemblies of polyfluorinated arylenediamines and 18-crown-6

Supramolecular 1D assemblies of polyfluorinated arylenediamines and 18-crown-6 Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2010, Volume: 59, Number: 2, Pages: 382-390 Pages count : DOI: 10.1007/s11172-010-0090-7

Tags

molecular crystals; supramolecular architecture; X-ray diffraction analysis; polyfluorinated compounds; arylenediamines; crown ether; melting heat; high-performance materials

Authors

Kusov S. Z. ¹ , Gatilov Yu. V. ¹ , Bagryanskaya I. Yu. ¹ , Romanenko G. V. ² , Vaganova T. A. ¹ , Shundrina I. K. ¹ , Malykhin E. V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, Inst Int Tomog Ctr, Novosibirsk 630090, Russia

Rods (1D assemblies) formed by alternate crown ether and arylenediamine molecules are the motif of the supramolecular architecture of crystals of molecular associates of 18-crown-6 with tetrafluoro-1,4- and -1,3-phenylenediamines, hexafluoro-2,6- and -2,7-naphthylenediamines. Molecules in the assemblies are arranged via H-bond predominantly between the crown ether oxygen atoms and the polyfluoroarene amino group hydrogen atoms. Influence of the amino groups mutual arrangement and the aromatic framework size on the crystal supramolecular architecture is characterized. Specific melting heats of the crystalline 1D assemblies of para- and pseudo-para-arylenediamines are higher than those of meta- and pseudo-meta-analogs; the associates having higher melting heats selectively crystallize from solutions of isomeric phenylene- or naphthylenediamine mixtures.

Kusov S.Z. , Gatilov Y.V. , Bagryanskaya I.Y. , Romanenko G.V. , Vaganova T.A. , Shundrina I.K. , Malykhin E.V.
Supramolecular 1D assemblies of polyfluorinated arylenediamines and 18-crown-6
Russian Chemical Bulletin. 2010. V.59. N2. P.382-390. DOI: 10.1007/s11172-010-0090-7 WOS Scopus РИНЦ OpenAlex

Кусов С.З. , Гатилов Ю.В. , Багрянская И.Ю. , Романенко Г.В. , Ваганова Т.А. , Шундрина И.К. , Малыхин Е.В.
Супрамолекулярные 1d-ансамбли полифторированных арилендиаминов и 18-краун-6
Известия Академии наук. Серия химическая.(RUSS CHEM B+). 2010. №2. С.375. РИНЦ

Published print:	Feb 1, 2010
Published online:	May 18, 2010

Web of science:	WOS:000283994000010
Scopus:	2-s2.0-78649716728
Elibrary:	16716750
OpenAlex:	W2089880074

DB	Citing
Web of science	6
Scopus	5
Elibrary	6
OpenAlex	5