Chiral C-2-Symmetric Diimines with 4,5-Diazafluorene Units Full article
| Journal |
Molecules
, E-ISSN: 1420-3049 |
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| Output data | Year: 2019, Volume: 24, Number: 17, Article number : 3186, Pages count : DOI: 10.3390/molecules24173186 | ||||||
| Tags | pinocarvone oxime; 4,5-diazafluorenon-9-one; chiral dipinodiazafluorenone; aromatic diamines; stable chiral diimines | ||||||
| Authors |
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| Affiliations |
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Abstract:
A synthetic approach to a new group of stable chiral C-2-symmetric diimines with the 4,5-diazafluorene core has been developed based on condensation of dipinodiazafluorene with aromatic diamines. The chemical structures of new compounds were proven by spectroscopic methods and X-ray crystallography. All the compounds form solvates with organic solvents (chloroform, benzene, 1,4-dioxane) and water. Specific spectral data of the new compounds are explained using calculated data (DFT). Diimines of the pinodiazafluorene series give colored reactions with transition metal ions and can be regarded as prospective polydentate ligands with interesting luminescent and chiroptical properties.
Cite:
Vasilyev E.S.
, Bizyaev S.N.
, Komarov V.Y.
, Gatilov Y.V.
, Tkachev A.V.
Chiral C-2-Symmetric Diimines with 4,5-Diazafluorene Units
Molecules. 2019.
V.24. N17. 3186
. DOI: 10.3390/molecules24173186
WOS
Scopus
РИНЦ
OpenAlex
Chiral C-2-Symmetric Diimines with 4,5-Diazafluorene Units
Molecules. 2019.
V.24. N17. 3186
. DOI: 10.3390/molecules24173186
WOS
Scopus
РИНЦ
OpenAlex
Files:
Full text from publisher
Dates:
| Published online: | Sep 2, 2019 |
Identifiers:
| Web of science: | WOS:000488613700166 |
| Scopus: | 2-s2.0-85071736156 |
| Elibrary: | 41636829 |
| OpenAlex: | W2971583560 |