Unusual Reactions of (+)-Car-2-ene and (+)-Car-3-ene with Aldehydes on K10 Clay Научная публикация
| Журнал |
Helvetica Chimica Acta
ISSN: 0018-019X , E-ISSN: 1522-2675 |
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| Вых. Данные | Год: 2010, Том: 93, Номер: 11, Страницы: 2135-2150 Страниц : DOI: 10.1002/hlca.201000145 | ||||
| Ключевые слова | Aldehydes; Carenes; Catalysis; Density functional theory (DFT); Isobenzofuran; K10 Clay | ||||
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Реферат:
The reactions of (+)-car-2-ene (1) and (+)-car 3-ene (2) with aldehydes in the presence of montmorillonite clay were studied for the first time (Schemes 3 and 5) The major products of these reactions are optically active, substituted hexahydroisobenzofurans, probably formed as a result of an attack of the protonated aldehyde at the cyclopropane ring Quite unexpectedly, the products are cis-configured at the ring-fusion site the fact was established by means of quantum-chemical calculations and NMR data It appeared that the behavior of the 2 3 mixture 1/2 in reactions with aldehydes in the presence of K10 clay differed substantially from the reactivities of the corresponding individual monoterpenes
Библиографическая ссылка:
Il'ina I.V.
, Volcho K.P.
, Korchagina D.V.
, Salnikov G.E.
, Genaev A.M.
, Karpova E.V.
, Salakhutdinov N.F.
Unusual Reactions of (+)-Car-2-ene and (+)-Car-3-ene with Aldehydes on K10 Clay
Helvetica Chimica Acta. 2010. V.93. N11. P.2135-2150. DOI: 10.1002/hlca.201000145 WOS Scopus РИНЦ OpenAlex
Unusual Reactions of (+)-Car-2-ene and (+)-Car-3-ene with Aldehydes on K10 Clay
Helvetica Chimica Acta. 2010. V.93. N11. P.2135-2150. DOI: 10.1002/hlca.201000145 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 нояб. 2010 г. |
| Опубликована online: | 11 нояб. 2010 г. |
Идентификаторы БД:
| Web of science: | WOS:000285069500003 |
| Scopus: | 2-s2.0-78549266518 |
| РИНЦ: | 16631420 |
| OpenAlex: | W2002701112 |