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Carbonylation of Polyfluorobenzocyclobutenones in a SbF5 Medium Full article

Journal Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393
Output data Year: 2019, Volume: 55, Number: 8, Pages: 1103-1111 Pages count : 9 DOI: 10.1134/S1070428019080086
Tags carbonylation; polyfluorinated benzocyclobutenones; isochromenone; antimony pentafluoride
Authors Zonov Ya, V 1,2 , Karpov V.M. 1 , Mezhenkova T., V 1
Affiliations
1 (Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia

Abstract: The carbonylation of perfluoro-2-R-benzocyclobutenones (R = F, CF3, C2F5, C6F5) in a CO-SbF5 system is accompanied by transformations of the four-membered cycle in the substrate to form polyfluorinated 1H-isochromene derivatives. The reaction of perfluoro-2-R-benzocyclobutenes (R = F, CF3, C2F5) with (CF3CO)(2)O or CF3COOH in a SbF5 medium in a sealed ampule involves formation of polyfluorobenzocyclobutenones and their carbonylation under the reaction conditions.
Cite: Zonov Y.V. , Karpov V.M. , Mezhenkova T.,.V.
Carbonylation of Polyfluorobenzocyclobutenones in a SbF5 Medium
Russian Journal of Organic Chemistry. 2019. V.55. N8. P.1103-1111. DOI: 10.1134/S1070428019080086 WOS Scopus РИНЦ OpenAlex
Original: Зонов Я.В. , Карпов В.М. , Меженкова Т.В.
Карбонилирование полифторбензоциклобутенонов в среде SBF5
Журнал органической химии (RUSS J ORG CHEM+). 2019. Т.55. №8. С.1193-1202. DOI: 10.1134/S0514749219080081 РИНЦ OpenAlex
Dates:
Published print: Aug 1, 2019
Published online: Oct 7, 2019
Identifiers:
Web of science: WOS:000489050100008
Scopus: 2-s2.0-85073061517
Elibrary: 41679517
OpenAlex: W2980266080
Citing:
DB Citing
Web of science 6
Scopus 6
Elibrary 6
OpenAlex 8
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