Synthesis and Properties of the Cu(II) Complexes with Chiral Bis{(E)-[(1S,4R)-Delta(7,8)-1-Amino-2-para-Menthalidene]aminohydroxy}methane (L - a Derivative of Natural Terpenoid (R)-(+)-Limonene). Crystal Structure of the [Cu(L)(mu-Cl)CuCl3]center dot iso-PrOH Solvate Full article
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284 |
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| Output data | Year: 2009, Volume: 35, Number: 3, Pages: 200-209 Pages count : 10 DOI: 10.1134/S1070328409030075 | ||||
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Abstract:
The Cu2LCl4 complex (I) with chiral bis{(E)-[(1S,4R)-Delta(7,8)-1-amino-2-para-menthalidene]aminohydroxy} methane (L - a derivative of natural monoterpenoid (R)-(+)-limonene) is synthesized. The crystal structure of the solvate of complex I [Cu(L)(mu-Cl)CuCl3] center dot iso-PrOH (II) is determined by X-ray diffraction analysis. Structure II is based on molecules of the [Cu(L)(mu-Cl)CuCl3] binuclear complexes in which L is the tetradentate cycle-forming ligand. One Cl atom manifests the bridging function. The CuN4Cl coordination unit is a square pyramid, and CuCl 4 is a distorted tetrahedron. The iso-PrOH molecules are localized in cavities between the layers of structure II. The mu(eff) value for complex I is 2.56 mu B and indicates the absence of an appreciable interaction between the Cu2+ ions in the Cu(II)-Cl-Cu(II) exchange cluster. The compound CuLCl2 center dot H2O (III) is synthesized. The mu(eff) value for compound III is 1.6 mu B. Complexes I and III are studied by EPR and IR spectroscopy.
Cite:
Kokina T.E.
, Glinskaya L.A.
, Klevtsova R.F.
, Boguslavskii E.G.
, Sheludyakova L.A.
, Bisyaev S.N.
, Tkachev A.V.
, Larionov S.V.
Synthesis and Properties of the Cu(II) Complexes with Chiral Bis{(E)-[(1S,4R)-Delta(7,8)-1-Amino-2-para-Menthalidene]aminohydroxy}methane (L - a Derivative of Natural Terpenoid (R)-(+)-Limonene). Crystal Structure of the [Cu(L)(mu-Cl)CuCl3]center dot iso-PrOH Solvate
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009. V.35. N3. P.200-209. DOI: 10.1134/S1070328409030075 WOS Scopus РИНЦ OpenAlex
Synthesis and Properties of the Cu(II) Complexes with Chiral Bis{(E)-[(1S,4R)-Delta(7,8)-1-Amino-2-para-Menthalidene]aminohydroxy}methane (L - a Derivative of Natural Terpenoid (R)-(+)-Limonene). Crystal Structure of the [Cu(L)(mu-Cl)CuCl3]center dot iso-PrOH Solvate
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009. V.35. N3. P.200-209. DOI: 10.1134/S1070328409030075 WOS Scopus РИНЦ OpenAlex
Original:
Кокина Т.Е.
, Глинская Л.А.
, Клевцова Р.Ф.
, Богуславский Е.Г.
, Шелудякова Л.А.
, Бизяев С.Н.
, Ткачев А.В.
, Ларионов С.В.
Синтез и свойства комплексов Cu(II) с хиральным бис-{(e)-[(1S,4R)- 7,8-1-амино-2-пара-менталиден]аминогидрокси}метаном (l) производным природного терпеноида (R)-(+)-лимонена. кристаллическая структура сольвата [Cu(l)( -Cl)CuCl3] · изо-PrOH
Координационная химия (RUSS J COORD CHEM+). 2009. Т.35. №3. С.202-211. РИНЦ
Синтез и свойства комплексов Cu(II) с хиральным бис-{(e)-[(1S,4R)- 7,8-1-амино-2-пара-менталиден]аминогидрокси}метаном (l) производным природного терпеноида (R)-(+)-лимонена. кристаллическая структура сольвата [Cu(l)( -Cl)CuCl3] · изо-PrOH
Координационная химия (RUSS J COORD CHEM+). 2009. Т.35. №3. С.202-211. РИНЦ
Dates:
| Published print: | Mar 1, 2009 |
| Published online: | Mar 29, 2009 |
Identifiers:
| Web of science: | WOS:000265733800007 |
| Scopus: | 2-s2.0-63749099726 |
| Elibrary: | 13603554 |
| OpenAlex: | W2020608332 |