Synthesis of binuclear complexes of PdCl2 with chiral alpha,alpha'-diamino-meta-xylene dioximes H2L1, H2L2, and H2L3, the derivatives of the terpenes (+)-3-carene, (R)-(+)-limonene, and (S)-(-)-alpha-pinene. Crystal structure of [Pd-2(H2L1)Cl-4] Full article
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284 |
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| Output data | Year: 2009, Volume: 35, Number: 4, Pages: 286-295 Pages count : 10 DOI: 10.1134/S1070328409040095 | ||||
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Abstract:
Chiral alpha,alpha'-diamino-meta-xylene dioximes H2L1, H2L2, and H2L3 were obtained from the naturally occurring terpenoids (+)-3-carene, (R)-(+)-limonene, and (S)-(-)-alpha-pinene, respectively. Reactions of these ligands with PdCl2 gave the diamagnetic complexes Pd-2(H2L1)Cl-4 (I), Pd-2(H2L2)Cl-4 (II), and Pd-2(H2L3)Cl-4 (III). According to X-ray diffraction data, the crystal structure of complex I consists of acentric binuclear molecules [Pd-2(H2L1)Cl-4]. The coordination polyhedron PdN2Cl2 is a square distorted in a tetrahedral manner (trapezium) made up of two N atoms of the tetradentate bridging cyclic ligand H2L1 and two Cl atoms. The fragments PdCl2 in the complex are cis to each other. According to the H-1 NMR spectra of complexes I-III in CDCl3, the organic ligands are coordinated through the N atoms; in solution, the complexes exist in several forms.
Cite:
Larionov S.V.
, Tkachev A.V.
, Myachina L.I.
, Savel'eva Z.A.
, Glinskaya L.A.
, Klevtsova R.F.
, Agafontsev A.M.
, Bizyaev S.N.
Synthesis of binuclear complexes of PdCl2 with chiral alpha,alpha'-diamino-meta-xylene dioximes H2L1, H2L2, and H2L3, the derivatives of the terpenes (+)-3-carene, (R)-(+)-limonene, and (S)-(-)-alpha-pinene. Crystal structure of [Pd-2(H2L1)Cl-4]
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009. V.35. N4. P.286-295. DOI: 10.1134/S1070328409040095 WOS Scopus РИНЦ OpenAlex
Synthesis of binuclear complexes of PdCl2 with chiral alpha,alpha'-diamino-meta-xylene dioximes H2L1, H2L2, and H2L3, the derivatives of the terpenes (+)-3-carene, (R)-(+)-limonene, and (S)-(-)-alpha-pinene. Crystal structure of [Pd-2(H2L1)Cl-4]
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009. V.35. N4. P.286-295. DOI: 10.1134/S1070328409040095 WOS Scopus РИНЦ OpenAlex
Original:
Ларионов С.В.
, Ткачев А.В.
, Мячина Л.И.
, Савельева З.А.
, Глинская Л.А.
, Клевцова Р.Ф.
, Агафонцев А.М.
, Бизяев С.Н.
Синтез двухъядерных комплексов PdCl2 с хиральными мета- -диаминоксилолдиоксимами H2L1, H2L2, H2L3 производными терпенов (+)-3-карена, (R)-(+)-лимонена и (S)-( )- -пинена. кристаллическая структура [Pd2(H2L1)Cl4]
Координационная химия (RUSS J COORD CHEM+). 2009. Т.35. №4. С.291-300. РИНЦ
Синтез двухъядерных комплексов PdCl2 с хиральными мета- -диаминоксилолдиоксимами H2L1, H2L2, H2L3 производными терпенов (+)-3-карена, (R)-(+)-лимонена и (S)-( )- -пинена. кристаллическая структура [Pd2(H2L1)Cl4]
Координационная химия (RUSS J COORD CHEM+). 2009. Т.35. №4. С.291-300. РИНЦ
Dates:
| Published print: | Apr 1, 2009 |
| Published online: | May 3, 2009 |
Identifiers:
| Web of science: | WOS:000265734100009 |
| Scopus: | 2-s2.0-65449128077 |
| Elibrary: | 13601170 |
| OpenAlex: | W2118050575 |