Carbocationic Rearrangements of 6b,7,8,8a-Tetramethyl-6b,8a-dihydrocyclobut[a]acenaphthylene: Effect of Medium Acidity Научная публикация
| Журнал |
Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Вых. Данные | Год: 2009, Том: 45, Номер: 8, Страницы: 1175-1180 Страниц : 6 DOI: 10.1134/S1070428009080107 | ||
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Реферат:
Rearrangements of 6b,7,8,.8a-tetramethyl-6b,8a-dihydrocyclobut[a]acenaphthylene in acids were investigated by NMR spectroscopy. The initially formed 3b,4-exo,4a,5-tetramethyl-3b,4,4a,5-tetrahydro-4H-cyclopropa[a]phenalen-5-yl cation and its endo-epimer rearranged into carbocations of phenalenyl type. Therewith the direction and the rate of rearrangement sharply changed at relatively small variations in the medium acidity.
Библиографическая ссылка:
Bushmelev V.A.
, Genaev A.M.
, Sal'nikov G.E.
, Shubin V.G.
Carbocationic Rearrangements of 6b,7,8,8a-Tetramethyl-6b,8a-dihydrocyclobut[a]acenaphthylene: Effect of Medium Acidity
Russian Journal of Organic Chemistry. 2009. V.45. N8. P.1175-1180. DOI: 10.1134/S1070428009080107 WOS Scopus РИНЦ OpenAlex
Carbocationic Rearrangements of 6b,7,8,8a-Tetramethyl-6b,8a-dihydrocyclobut[a]acenaphthylene: Effect of Medium Acidity
Russian Journal of Organic Chemistry. 2009. V.45. N8. P.1175-1180. DOI: 10.1134/S1070428009080107 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 авг. 2009 г. |
| Опубликована online: | 27 сент. 2009 г. |
Идентификаторы БД:
| Web of science: | WOS:000269887800011 |
| Scopus: | 2-s2.0-70349514896 |
| РИНЦ: | 15301228 |
| OpenAlex: | W2030879838 |