Nitrosonium Complexes of Triptycene

Nitrosonium Complexes of Triptycene Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2009, Volume: 45, Number: 9, Pages: 1344-1348 Pages count : 5 DOI: 10.1134/S1070428009090061

Authors

Borodkin G.I. ¹ , Elanov I.R. ¹ , Andreev R.V. ¹ , Shubin V.G. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

According to the H-1 and C-13 NMR data, triptycene reacts with nitrosonium tetrachloroaluminate to form positively charged pi-complexes with one and two nitrosonium ions, which are rapidly (on the NMR time scale) converted into each other. DFT quantum-chemical calculations with Lambda 02 basis set indicated higher stability of singly charged complexes relative to doubly charged. Addition of three nitrosonium ions to triptycene molecule is unfavorable from the energy viewpoint.

Borodkin G.I. , Elanov I.R. , Andreev R.V. , Shubin V.G.
Nitrosonium Complexes of Triptycene
Russian Journal of Organic Chemistry. 2009. V.45. N9. P.1344-1348. DOI: 10.1134/S1070428009090061 WOS Scopus РИНЦ OpenAlex

Published print:	Sep 1, 2009
Published online:	Oct 13, 2009

Web of science:	WOS:000270744600006
Scopus:	2-s2.0-84877100562
Elibrary:	21894286
OpenAlex:	W2018597837

DB	Citing
Web of science	2
Scopus	3
Elibrary	2
OpenAlex	3