Paramagnetic complexes of magnesium as mediators in enzymatic ATP synthesis: DFT calculations of magnetic parameters Научная публикация
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Chemical Physics Letters
ISSN: 0009-2614 , E-ISSN: 1873-4448 |
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| Вых. Данные | Год: 2009, Том: 483, Номер: 1-3, Страницы: 77-80 Страниц : 4 DOI: 10.1016/j.cplett.2009.10.044 | ||||||
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Реферат:
Magnetic parameters (g-factors, hyperfine coupling constants a(Mg-25) and a(P-31)) of paramagnetic pyrophosphate and hydrate magnesium complexes, which model those in catalytic site of the ATP synthesizing enzymes, are calculated. Both g-factors and HFC constants a(P-31) of the paramagnetic pyrophosphate magnesium complexes are identical to those of the pyrophosphate radical. It demonstrates that namely terminal PO3 group of the liganded ADP in the complex Mg2+(ADP)(3) donates electron to the Mg(H2O)(n)(2+) ion in the primary reaction of the ion-radical mechanism of enzymatic ATP synthesis. (C) 2009 Elsevier B.V. All rights reserved.
Библиографическая ссылка:
Buchachenko A.L.
, Shchegoleva L.N.
, Breslavskaya N.N.
Paramagnetic complexes of magnesium as mediators in enzymatic ATP synthesis: DFT calculations of magnetic parameters
Chemical Physics Letters. 2009. V.483. N1-3. P.77-80. DOI: 10.1016/j.cplett.2009.10.044 WOS Scopus РИНЦ OpenAlex
Paramagnetic complexes of magnesium as mediators in enzymatic ATP synthesis: DFT calculations of magnetic parameters
Chemical Physics Letters. 2009. V.483. N1-3. P.77-80. DOI: 10.1016/j.cplett.2009.10.044 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 нояб. 2009 г. |
Идентификаторы БД:
| Web of science: | WOS:000271758000014 |
| Scopus: | 2-s2.0-72049093972 |
| РИНЦ: | 15297224 |
| OpenAlex: | W2066868712 |