Skeletal transformations of perfluorinated 2,2-diethyl- and 2-ethyl-2-phenylbenzocyclobutenones under the action of antimony pentafluoride Научная публикация
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Вых. Данные | Год: 2008, Том: 129, Номер: 12, Страницы: 1206-1208 Страниц : 3 DOI: 10.1016/j.jfluchem.2008.08.002 | ||
| Ключевые слова | Skeletal transformations; Perfluoro-2,2-diethyl-benzocyclobutenone; Perfluoro-2-ethyl-2-phenylbenzocyclobutenone; Antimony pentafluoride; NMR spectroscopy | ||
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Реферат:
Perfluoro-2-ethyl-2-phenylbenzocyclobutenone heated with SbFs at 70 degrees C and then treated with water, forms perfluoro-3-ethyl-3-phenylphthalide. In contrast to this, heating of perfluoro-2,2-diethylbenzocyclobutenone with SbFs at 70 C gives, after treatment of the reaction mixture with water, perfluoro-2-(pent-2-en-3-yl)benzoic acid. When the reaction temperature is raised to 125 C, a solution of a salt of perfluoro-4-ethyl-3-methylisochromenyl cation is obtained. Hydrolysis of the solution of the salt gives perfluoro-4-ethyl-3-methylisochromen-1-one. (c) 2008 Elsevier B.V. All rights reserved.
Библиографическая ссылка:
Zonov Y.V.
, Mezhenkova T.V.
, Karpov V.M.
, Platonov V.E.
Skeletal transformations of perfluorinated 2,2-diethyl- and 2-ethyl-2-phenylbenzocyclobutenones under the action of antimony pentafluoride
Journal of Fluorine Chemistry. 2008. V.129. N12. P.1206-1208. DOI: 10.1016/j.jfluchem.2008.08.002 WOS Scopus РИНЦ OpenAlex
Skeletal transformations of perfluorinated 2,2-diethyl- and 2-ethyl-2-phenylbenzocyclobutenones under the action of antimony pentafluoride
Journal of Fluorine Chemistry. 2008. V.129. N12. P.1206-1208. DOI: 10.1016/j.jfluchem.2008.08.002 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 дек. 2008 г. |
Идентификаторы БД:
| Web of science: | WOS:000261846500013 |
| Scopus: | 2-s2.0-56049083242 |
| РИНЦ: | 13576263 |
| OpenAlex: | W2949967559 |