Synthesis and structure of Cu(II) and Pd(II) coordination compounds with chiral alpha-thiooxime, a derivative of natural terpenoid (-)-alpha-pinene Full article
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Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 |
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| Output data | Year: 2008, Volume: 53, Number: 5, Pages: 696-703 Pages count : 8 DOI: 10.1134/S0036023608050069 | ||||
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Abstract:
The paramagnetic complex Cu(HL)Cl-2(I) (mu(eff) = 1.88 mu(B)) and the diamagnetic complex Pd(HL)Cl-2(II) with chiral alpha-thiooxime, a derivative of natural terpenoid (-)-alpha-pinene (HL), were synthesized. The crystal structures of these complexes were determined from single-crystal X-ray diffraction data (X8 APEX diffractometer, MoK alpha radiation, 2975 F-hkl , R = 0.0258 for I and 3270 F-hkl , R = 0.0222 for II). The crystals of complex I are monoclinic, a = 9.3376(3) angstrom, b = 6.8619(2) angstrom, c = 14.6540(5) angstrom, beta = 97.814(1)degrees, V = 930.22(5) angstrom(3), Z = 2, rho(calc) = 1.513 g/cm(3), space group P2(1). The crystals of complex II are orthorhombic, a = 7.0084(6) angstrom, b = 9.2113(9) angstrom, c = 29.081(3) angstrom, V = 1877.4(3) angstrom(3), Z = 4, rho(calc) = 1.651 g/cm(3), space group P2(1)2(1)2(1). The structures are composed of mononuclear molecules. The coordination cores MNSCl2 (M = Cu, Pd) are tetrahedrally distorted squares. According to NMR data, complex II has a similar structure in a CDCl3 solution. The intermolecular contacts in structure I generate supramolecular polymeric ribbons lying parallel to axis b. No short intermolecular contacts are present in complex II.
Cite:
Kokina T.E.
, Klevtsova R.F.
, Glinskaya L.A.
, Agafontsev A.M.
, Tkachev A.V.
, Larionov S.V.
Synthesis and structure of Cu(II) and Pd(II) coordination compounds with chiral alpha-thiooxime, a derivative of natural terpenoid (-)-alpha-pinene
Russian Journal of Inorganic Chemistry. 2008. V.53. N5. P.696-703. DOI: 10.1134/S0036023608050069 WOS Scopus РИНЦ OpenAlex
Synthesis and structure of Cu(II) and Pd(II) coordination compounds with chiral alpha-thiooxime, a derivative of natural terpenoid (-)-alpha-pinene
Russian Journal of Inorganic Chemistry. 2008. V.53. N5. P.696-703. DOI: 10.1134/S0036023608050069 WOS Scopus РИНЦ OpenAlex
Original:
Кокина Т.Е.
, Клевцова Р.Ф.
, Глинская Л.А.
, Агафонцев А.М.
, Ткачев А.В.
, Ларионов С.В.
СИНТЕЗ И СТРОЕНИЕ КООРДИНАЦИОННЫХ СОЕДИНЕНИЙ CU(II) И PD(II) С ХИРАЛЬНЫМ -ТИООКСИМОМ ПРОИЗВОДНЫМ ПРИРОДНОГО ТЕРПЕНОИДА (-)- -ПИНЕНА
Журнал неорганической химии. 2008. Т.53. №5. С.758-765. РИНЦ
СИНТЕЗ И СТРОЕНИЕ КООРДИНАЦИОННЫХ СОЕДИНЕНИЙ CU(II) И PD(II) С ХИРАЛЬНЫМ -ТИООКСИМОМ ПРОИЗВОДНЫМ ПРИРОДНОГО ТЕРПЕНОИДА (-)- -ПИНЕНА
Журнал неорганической химии. 2008. Т.53. №5. С.758-765. РИНЦ
Dates:
| Published print: | May 1, 2008 |
| Published online: | May 29, 2008 |
Identifiers:
| Web of science: | WOS:000256328800006 |
| Scopus: | 2-s2.0-44349180222 |
| Elibrary: | 13591031 |
| OpenAlex: | W1975602538 |