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Reaction of perfluorobenzocycloalkenes with SiO(2)-SbF(5) and skeleton transformations of their carbonyl derivatives in SbF(5) medium Научная публикация

Журнал Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393
Вых. Данные Год: 2008, Том: 44, Номер: 2, Страницы: 202-217 Страниц : DOI: 10.1134/S107042800802005X
Авторы Zonov Ya. V. , Karpov V. M. , Platonov V. E. , Gatilov Yu. V.
Организации
1 (Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

Реферат: The reaction of perfluorinated benzocyclobutene and tetraline with SiO(2)-SbF(5) led to the formation in a high yield of their mono- and further dicarbonyl derivatives. The monocarbonyl derivatives on heating with SbF(5) underwent disproportionation into the corresponding perfluorobenzocycloalkenes and diketones. Both mono- and diketones in the SbF5 medium are liable to suffer Skeleton rearrangements yielding five- and six-membered oxygen-containing heterocycles and/or products of the opening of the alicyclic fragment of the substrate, and from the perfluorobenzocyclobutenone compounds were also obtained with a number of carbon atoms greater than that of the initial ketone.
Библиографическая ссылка: Zonov Y.V. , Karpov V.M. , Platonov V.E. , Gatilov Y.V.
Reaction of perfluorobenzocycloalkenes with SiO(2)-SbF(5) and skeleton transformations of their carbonyl derivatives in SbF(5) medium
Russian Journal of Organic Chemistry. 2008. V.44. N2. P.202-217. DOI: 10.1134/S107042800802005X WOS Scopus РИНЦ OpenAlex
Оригинальная: Зонов Я.В. , Карпов В.М. , Платонов В.Е. , Гатилов Ю.В.
Взаимодействие перфторбензоциклоалкенов с sic2-sbf5 и скелетные превращения их карбонильных производных в среде sbf5
Журнал органической химии (RUSS J ORG CHEM+). 2008. Т.44. №2. С.212-226. РИНЦ
Даты:
Опубликована в печати: 1 февр. 2008 г.
Опубликована online: 19 янв. 2011 г.
Идентификаторы БД:
Web of science: WOS:000254140900005
Scopus: 2-s2.0-43249099343
РИНЦ: 13566388
OpenAlex: W2111512249
Цитирование в БД:
БД Цитирований
Web of science 11
Scopus 10
РИНЦ 10
OpenAlex 12
Альметрики: