Sciact
  • EN
  • RU

Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure Full article

Journal Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296
Output data Year: 2007, Volume: 80, Number: 9, Pages: 1515-1522 Pages count : DOI: 10.1134/S1070427207090145
Authors Malinskaya M. Yu. , Ivancheva N. I. , Oleinik I. I. , Tolstikov G. A. , Ivanchev S. S.
Affiliations
1 (Данные Web of science) Russian Acad Sci, Boreskov Inst Catl, St Petersburg Branch, Siberian Div, St Petersburg, Russia
2 (Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Div, Novosibirsk, Russia

Abstract: Polymerization of ethylene at 30-70 degrees C in the presence of catalytic systems based on titanium bis(phenoxy imine) complexes of various structures, activated with methylalumoxane, was studied. An attempt was made to systematize the effect of substituents in ligands, to find correlations, to account for the results obtained, and to reveal conditions under which the reaction occurs by the "living" polymerization mechanism. Some properties and structural features of the polyethylenes obtained were determined.
Cite: Malinskaya M.Y. , Ivancheva N.I. , Oleinik I.I. , Tolstikov G.A. , Ivanchev S.S.
Catalytic activity of systems based on titanium bis(phenoxy imine) complexes: Effect of the ligand structure
Russian Journal of Applied Chemistry. 2007. V.80. N9. P.1515-1522. DOI: 10.1134/S1070427207090145 WOS Scopus РИНЦ OpenAlex
Dates:
Published print: Sep 1, 2007
Identifiers:
Web of science: WOS:000250622800014
Scopus: 2-s2.0-35448957742
Elibrary: 13540394
OpenAlex: W2000568502
Citing:
DB Citing
Web of science 8
Scopus 7
Elibrary 6
OpenAlex 8
Altmetrics: