The high-temperature alicyclic ring contraction of 1,1-dichloroperfluorotetralin and the alicyclic ring opening of 1,1-dichloroperfluorobenzocyclobutene Full article
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Output data | Year: 2007, Volume: 128, Number: 7, Pages: 714-717 Pages count : DOI: 10.1016/j.jfluchem.2007.02.015 | ||
| Tags | fluorinated; tetralin; benzocyclobutene; pyrolysis; ring contraction; ring opening | ||
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Abstract:
The pyrolysis of 1,1-dichloroperfluorotetralin (4) in a stream of argon gives a mixture contained perfluoro-1-methyleneindan (1), perfluoro-3-methylindene (6), 1,1-dichloroperfluoroindan (2) and perfluoroindene (7), while copyrolysis of tetralin 4 with CHClF2 gives a mixture of compounds 1, 6 in the absence of compounds 2 and 7. 1-Chloro-2-(1-chloro-2,2-difluorovinyl)-3,4,5,6-tetrafluorobenzene (12) is formed in the pyrolysis of 1,1-dichloroperfluorobenzocyclobutene (5) in a stream of argon as well as in a stream of CHClF2. (c) 2007 Elsevier B.V. All rights reserved.
Cite:
Karpov V.M.
, Mezhenkova T.V.
, Platonov V.E.
The high-temperature alicyclic ring contraction of 1,1-dichloroperfluorotetralin and the alicyclic ring opening of 1,1-dichloroperfluorobenzocyclobutene
Journal of Fluorine Chemistry. 2007. V.128. N7. P.714-717. DOI: 10.1016/j.jfluchem.2007.02.015 WOS Scopus РИНЦ OpenAlex
The high-temperature alicyclic ring contraction of 1,1-dichloroperfluorotetralin and the alicyclic ring opening of 1,1-dichloroperfluorobenzocyclobutene
Journal of Fluorine Chemistry. 2007. V.128. N7. P.714-717. DOI: 10.1016/j.jfluchem.2007.02.015 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Jul 1, 2007 |
Identifiers:
| Web of science: | WOS:000248429900006 |
| Scopus: | 2-s2.0-34250774399 |
| Elibrary: | 13539751 |
| OpenAlex: | W2950181160 |