Nickel(II) and copper(II) complexes with chiral bis-alpha-thiooxime, the derivative of natural terpenoid (+)-3-carene: Synthesis and structures Full article
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284 |
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| Output data | Year: 2007, Volume: 33, Number: 7, Pages: 514-522 Pages count : 9 DOI: 10.1134/S107032840707007X | ||||||
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Abstract:
Chiral bis-alpha-thiooxime (H2L1), the derivative of the natural monoterpenoid (+)-3-carene, was synthesized and used to prepare paramagnetic complexes of the composition M(H2L1)Cl-2 (M=Ni, Cu). The crystal structures of [Ni(H2L1)Cl-2] (I) and [Cu(H2L1)Cl-2] (II) were determined by X-ray diffraction analysis. Crystals I and II consist of mononuclear acentric molecules. The Ni2+ ion in a molecule of complex I coordinates two N atoms and two S atoms of a tetradentate chelating ligand (the H2L1 molecule) and two Cl atoms. The NiCl2N2S2 coordination core forms octahedron compressed along the apical N atoms. In a molecule of complex II, the Cu2+ ion coordinates two S atoms and the N atom of a tridentate chelating H2L1 ligand and two Cl atoms. The CuCl2NS2 coordination core forms a trigonal bipyramid.
Cite:
Larionov S.V.
, Kokina T.E.
, Agafontsev A.M.
, Gorshkov N.B.
, Tkachev A.V.
, Klevtsova R.F.
, Glinskaya L.A.
Nickel(II) and copper(II) complexes with chiral bis-alpha-thiooxime, the derivative of natural terpenoid (+)-3-carene: Synthesis and structures
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2007. V.33. N7. P.514-522. DOI: 10.1134/S107032840707007X WOS Scopus РИНЦ OpenAlex
Nickel(II) and copper(II) complexes with chiral bis-alpha-thiooxime, the derivative of natural terpenoid (+)-3-carene: Synthesis and structures
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2007. V.33. N7. P.514-522. DOI: 10.1134/S107032840707007X WOS Scopus РИНЦ OpenAlex
Original:
Ларионов С.В.
, Кокина Т.Е.
, Агафонцев А.М.
, Горшков Н.Б.
, Ткачев А.В.
, Клевцова Р.Ф.
, Глинская Л.А.
Синтез и строение координационных соединений Ni(II) и Cu(II) с хиральным бис- -тиооксимом производным природного терпеноида (+)-3-карена
Координационная химия (RUSS J COORD CHEM+). 2007. Т.33. №7. С.525-533. РИНЦ
Синтез и строение координационных соединений Ni(II) и Cu(II) с хиральным бис- -тиооксимом производным природного терпеноида (+)-3-карена
Координационная химия (RUSS J COORD CHEM+). 2007. Т.33. №7. С.525-533. РИНЦ
Dates:
| Published print: | Jul 1, 2007 |
Identifiers:
| Web of science: | WOS:000248329500007 |
| Scopus: | 2-s2.0-34547174607 |
| Elibrary: | 13564194 |
| OpenAlex: | W2078027984 |