Single crystal X-ray diffraction study of dioxane, pyrazine, and pyridine complexes of 3-(1-amino-2,2,2-trifluoroethylidene)2-imino-1,1,4,5,6,7-hexafluoroindan Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2007, Volume: 48, Number: 2, Pages: 310-317 Pages count : 8 DOI: 10.1007/s10947-007-0047-3 | ||
| Tags | polyfluorinated enaminoimines; indan; indene; synthesis; structure; X-ray diffraction analysis; tautomers; quantum chemical calculations | ||
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Abstract:
Single crystals of complexes of 3-(1-amino-2,2,2-trifluoroethylidene)-2-imino-1,1,4,5,6,7-hexafluoroindan (1) with 1,4-dioxane, pyrazine, and pyridine have been synthesized. Their structure was investigated by X-ray analysis. In crystals of the dioxane complex, compound 1 is present together with its tautomer - 2-amino-3-(1-imino-2,2,2-trifluoroethyl)-1,1,4,5,6,7-hexafluoroindene (1a), and these compounds are in an equilibrium ratio of similar to 60:40. Gas-phase quantum chemical calculations have been performed to examine the possibility of a tautomeric equilibrium of enaminoimine 1 in the corresponding complexes.
Cite:
Rybalova T.V.
, Karpov V.M.
, Platonov V.E.
, Gatilov Y.V.
Single crystal X-ray diffraction study of dioxane, pyrazine, and pyridine complexes of 3-(1-amino-2,2,2-trifluoroethylidene)2-imino-1,1,4,5,6,7-hexafluoroindan
Journal of Structural Chemistry. 2007. V.48. N2. P.310-317. DOI: 10.1007/s10947-007-0047-3 WOS Scopus РИНЦ OpenAlex
Single crystal X-ray diffraction study of dioxane, pyrazine, and pyridine complexes of 3-(1-amino-2,2,2-trifluoroethylidene)2-imino-1,1,4,5,6,7-hexafluoroindan
Journal of Structural Chemistry. 2007. V.48. N2. P.310-317. DOI: 10.1007/s10947-007-0047-3 WOS Scopus РИНЦ OpenAlex
Original:
Рыбалова Т.В.
, Карпов В.М.
, Платонов В.Е.
, Гатилов Ю.В.
Рентгеноструктурное исследование монокристаллов комплексов 3-(1-амино-2,2,2-трифторэтилиден)-2-имино-1,1,4,5,6,7-гексафториндана с диоксаном, пиразином и пиридином
Журнал структурной химии (J STRUCT CHEM+). 2007. Т.48. №2. С.318-324. РИНЦ
Рентгеноструктурное исследование монокристаллов комплексов 3-(1-амино-2,2,2-трифторэтилиден)-2-имино-1,1,4,5,6,7-гексафториндана с диоксаном, пиразином и пиридином
Журнал структурной химии (J STRUCT CHEM+). 2007. Т.48. №2. С.318-324. РИНЦ
Dates:
| Published print: | Mar 1, 2007 |
Identifiers:
| Web of science: | WOS:000248180000015 |
| Scopus: | 2-s2.0-34547552300 |
| Elibrary: | 13533951 |
| OpenAlex: | W2090773514 |