Synthesis and properties of copper(II) complexes with a chiral dioxatetraazamacrocyclic ligand based on a natural monoterpene, (+)-3-carene Full article
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Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 |
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| Output data | Year: 2007, Volume: 52, Number: 1, Pages: 42-45 Pages count : 4 DOI: 10.1134/S0036023607010081 | ||||
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Abstract:
The copper(II) compounds [CuL](NO3)(2) center dot H2O (I), [CuL](ClO4)(2) center dot H2O (II), CuLCl2 center dot 3H(2)O (III), and CuLBr2 center dot 4H(2)O (IV), where L is a chiral dioxatetraazamacrocyclic ligand based on the natural monoterpene (+)-3-carene, have been synthesized. According to IR and EPR spectroscopy, L acts as a tetradentate chelating ligand coordinated through the N atoms of the NH and C=N groups. The NO3- anions in I and the ClO4- anions in II are outer-sphere. I and II have a planar coordination core CuN4, III has a CuN4ClO coordination core, and IV has a CuN4Br2 coordination core.
Cite:
Larionov S.V.
, Myachina L.I.
, Sheludyakova L.A.
, Boguslavskii E.G.
, Bizyaev S.N.
, Tkachev A.V.
Synthesis and properties of copper(II) complexes with a chiral dioxatetraazamacrocyclic ligand based on a natural monoterpene, (+)-3-carene
Russian Journal of Inorganic Chemistry. 2007. V.52. N1. P.42-45. DOI: 10.1134/S0036023607010081 WOS Scopus РИНЦ OpenAlex
Synthesis and properties of copper(II) complexes with a chiral dioxatetraazamacrocyclic ligand based on a natural monoterpene, (+)-3-carene
Russian Journal of Inorganic Chemistry. 2007. V.52. N1. P.42-45. DOI: 10.1134/S0036023607010081 WOS Scopus РИНЦ OpenAlex
Original:
Ларионов С.В.
, Мячина Л.И.
, Шелудякова Л.А.
, Богуславский Е.Г.
, Бизяев С.Н.
, Ткачев А.В.
СИНТЕЗ И СВОЙСТВА КООРДИНАЦИОННЫХ СОЕДИНЕНИЙ МЕДИ(II) С ХИРАЛЬНЫМ ДИОКСАТЕТРААЗАМАКРОЦИКЛИЧЕСКИМ ЛИГАНДОМ НА ОСНОВЕ ПРИРОДНОГО МОНОТЕРПЕНА (+)-3-КАРЕНА
Журнал неорганической химии. 2007. Т.52. №1. С.47-50. РИНЦ
СИНТЕЗ И СВОЙСТВА КООРДИНАЦИОННЫХ СОЕДИНЕНИЙ МЕДИ(II) С ХИРАЛЬНЫМ ДИОКСАТЕТРААЗАМАКРОЦИКЛИЧЕСКИМ ЛИГАНДОМ НА ОСНОВЕ ПРИРОДНОГО МОНОТЕРПЕНА (+)-3-КАРЕНА
Журнал неорганической химии. 2007. Т.52. №1. С.47-50. РИНЦ
Dates:
| Published print: | Jan 1, 2007 |
Identifiers:
| Web of science: | WOS:000245665700008 |
| Scopus: | 2-s2.0-33846704939 |
| Elibrary: | 13534603 |
| OpenAlex: | W1967768754 |