Polyfluoroorganoboron-oxygen compounds. 5[1] Feasible routes to perfluoroalkyltrimethoxyborates M[CnF2n+1B(OMe)(3)](n >= 3) Научная публикация
| Журнал |
Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 |
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| Вых. Данные | Год: 2007, Том: 633, Номер: 4, Страницы: 647-652 Страниц : DOI: 10.1002/zaac.200600357 | ||||
| Ключевые слова | perfluoroalkylborates; perfluoroalkylation; perfluoroalkyl lithium compounds; NMR spectroscopy | ||||
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| Организации |
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Реферат:
A well applicable preparative method for lithium perfluoroalkyltrimethoxyborates, Li[CnF2n+1B(OMe)(3)] (n = 3, 4, 6), was elaborated which is based on the reaction of B(OMe)3 with CnF2n+1Li generated from CnF2n+1H and t-BuLi. Alternative perfluoroalkylation reactions of B(OMe)(3) with perfluoropropyllithium generated from C3F7I and RLi, perfluoropropylmagnesium bromide, or perfluoropropyltrimethylsilane and potassium fluoride gave less satisfactory results for M[C3F7B(OMe)(3)]. The conversion of M[CnF2n+1B(OMe)(3)] salts (M = Li, BrMg) into K[CnF2n+1B(OMe)(3)] salts and basic properties of the new salts are reported.
Библиографическая ссылка:
Adonin N.Y.
, Bardin V.V.
, Frohn H-J.
Polyfluoroorganoboron-oxygen compounds. 5[1] Feasible routes to perfluoroalkyltrimethoxyborates M[CnF2n+1B(OMe)(3)](n >= 3)
Zeitschrift fur Anorganische und Allgemeine Chemie. 2007. V.633. N4. P.647-652. DOI: 10.1002/zaac.200600357 WOS Scopus РИНЦ OpenAlex
Polyfluoroorganoboron-oxygen compounds. 5[1] Feasible routes to perfluoroalkyltrimethoxyborates M[CnF2n+1B(OMe)(3)](n >= 3)
Zeitschrift fur Anorganische und Allgemeine Chemie. 2007. V.633. N4. P.647-652. DOI: 10.1002/zaac.200600357 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована в печати: | 1 апр. 2007 г. |
Идентификаторы БД:
| Web of science: | WOS:000245182100025 |
| Scopus: | 2-s2.0-33947578042 |
| РИНЦ: | 13534788 |
| OpenAlex: | W1965070742 |