The dependence on temperature and concentration of Xe-129 NMR chemical shift values of organoxenon(II) salts [RXe][Y] and of the parent molecule XeF2 Full article
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Magnetic Resonance in Chemistry
ISSN: 0749-1581 , E-ISSN: 1097-458X |
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| Output data | Year: 2006, Volume: 44, Number: 6, Pages: 648-650 Pages count : DOI: 10.1002/mrc.1799 | ||||
| Tags | NMR; Xe-121 NMR; Xe-129 chemical shift values; organoxenon salts; xenon difluoride | ||||
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Abstract:
The dependence of the Xe-129 NMR chemical shift value of XeF2 on temperature and concentration was determined in a variety of prototypic media: in acidic (anhydrous HF, aHF), nonprotic but polar (dichloromethane), and basic (CD3CN-EtCN, 1: 3 v/v) solvents. The Xe-129 NMR spectra of a representative series of organoxenon(II) salts [RXe][Y] (R=C6F5, heptafluoro-1,4-cyclohexadien-1-yl (cyclo-1,4-C6F7), pentafluoro-1,4-cyclohexadien-3-on-1-yl (cyclo-3-O-1,4-C6F5) CF2=C(CF3), (CF3)(2)CFC=C C4H9C=C; Y=BF4, AsF6) in aHF showed, compared with XeF2 -aHF, a quantitatively less distinct but qualitatively related dependence of delta(Xe-129) vs temperature. The dependence of their delta(Xe-129) values on concentration in aHF is negligible. An explanation for the different behavior of [RXe][Y] and XeF2 is offered. Copyright (C) 2006 John Wiley & Sons, Ltd.
Cite:
Bardin V.V.
, Frohn H-J.
The dependence on temperature and concentration of Xe-129 NMR chemical shift values of organoxenon(II) salts [RXe][Y] and of the parent molecule XeF2
Magnetic Resonance in Chemistry. 2006. V.44. N6. P.648-650. DOI: 10.1002/mrc.1799 WOS Scopus РИНЦ OpenAlex
The dependence on temperature and concentration of Xe-129 NMR chemical shift values of organoxenon(II) salts [RXe][Y] and of the parent molecule XeF2
Magnetic Resonance in Chemistry. 2006. V.44. N6. P.648-650. DOI: 10.1002/mrc.1799 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | May 1, 2006 |
Identifiers:
| Web of science: | WOS:000237884900013 |
| Scopus: | 2-s2.0-33744478443 |
| Elibrary: | 13518950 |
| OpenAlex: | W2087883457 |