Molecular complexes of octafluoronaphthalene with catenated chalcogen-nitrogen compounds C6H5-X-N=S=N-SiMe3 (X = S, Se) Full article
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Output data | Year: 2006, Volume: 127, Number: 3, Pages: 437-442 Pages count : 6 DOI: 10.1016/j.jfluchem.2005.11.021 | ||||||
| Tags | octafluoronaphthalene; chalcogen-nitrogen compounds; molecular complexes; pi-stacking interactions; X-ray structure determination | ||||||
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Abstract:
Mismatched molecular 1:1 complexes of C10F8 with catenated chalcogen-nitrogen compounds C6H5-X-N=S=N-SiMe3 (X=S, Se) were prepared and characterized by X-ray crystallography. The complexes provide examples of structurally non-rigid polyheteroatom molecules involved in non-covalent arene-polyfluoroarene pi-stacking interactions. In going from homocrystals to the co-crystals, the molecular Z, E configuration of the catenated compounds changes from noticeibly non-planar to perfectly planar, i.e. C10F8 acts as "molecular iron". On the other hand, C10H8 does not produce complexes with C6F5-X-N=S=N-SiMe3 (X = S, Se). (c) 2006 Elsevier B.V. All rights reserved.
Cite:
Makarov A.Y.
, Lork E.
, Mews R.
, Zibarev A.V.
Molecular complexes of octafluoronaphthalene with catenated chalcogen-nitrogen compounds C6H5-X-N=S=N-SiMe3 (X = S, Se)
Journal of Fluorine Chemistry. 2006. V.127. N3. P.437-442. DOI: 10.1016/j.jfluchem.2005.11.021 WOS Scopus РИНЦ OpenAlex
Molecular complexes of octafluoronaphthalene with catenated chalcogen-nitrogen compounds C6H5-X-N=S=N-SiMe3 (X = S, Se)
Journal of Fluorine Chemistry. 2006. V.127. N3. P.437-442. DOI: 10.1016/j.jfluchem.2005.11.021 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Mar 1, 2006 |
Identifiers:
| Web of science: | WOS:000236926300019 |
| Scopus: | 2-s2.0-33645379466 |
| Elibrary: | 13505945 |
| OpenAlex: | W2129442095 |