The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene Научная публикация
| Журнал |
ChemistrySelect
ISSN: 2365-6549 |
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| Вых. Данные | Год: 2020, Том: 5, Номер: 29, Страницы: 9277-9280 Страниц : 4 DOI: 10.1002/slct.202001852 | ||||
| Ключевые слова | Carbocations reactivity; superacids; IR spectroscopy | ||||
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Реферат:
The first two stages of the chemical interaction of a benzyl cation with a weak base, benzene, have been established. A key point in the reactivity of this cation is its ability to act as a strong protonating agent, turning itself to highly reactive carbene molecule, which then interacts with the available initial carbocation. The second step is mostly responsible for the high reactivity of the unsaturated carbocation. Further studies will show whether this mechanism is typical for saturated alkane and allyl-type carbocations.
Библиографическая ссылка:
Stoyanov E.S.
, Stoyanova I.V.
The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene
ChemistrySelect. 2020. V.5. N29. P.9277-9280. DOI: 10.1002/slct.202001852 WOS Scopus РИНЦ OpenAlex
The Mechanism of High Reactivity of Benzyl Carbocation, C6H5CH2+, during Interaction with Benzene
ChemistrySelect. 2020. V.5. N29. P.9277-9280. DOI: 10.1002/slct.202001852 WOS Scopus РИНЦ OpenAlex
Даты:
| Опубликована online: | 5 авг. 2020 г. |
| Опубликована в печати: | 7 авг. 2020 г. |
Идентификаторы БД:
| Web of science: | WOS:000557666500047 |
| Scopus: | 2-s2.0-85089200903 |
| РИНЦ: | 45382204 |
| OpenAlex: | W3047278272 |