Synthesis and crystal and molecular structure of the complex [Cu(HL)Cl](2)[CuCl4], where HL is optically active terpenic (1S,3S,6R)-3-[N-(3-aminopropyl)aminol-4-caranone (E)-oxime Full article
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Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 |
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| Output data | Year: 2005, Volume: 50, Number: 5, Pages: 711-714 Pages count : 4 | ||||
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Abstract:
A new paramagnetic compound [Cu(HL)Cl](2)[CuCl4], where HL is optically active (1S,3S,6R)-3-[N-(3-aminopropyl)amino]-4-caranone (E)-oxime, was synthesized. Its crystal and molecular structure was determined by X-ray diffraction. The compound consists of complex cations [Cu(HL)Cl](+) and outer-sphere tetrahedral anions [CuCl4](2-). In the complex cation, the Cu2+, ion coordinates three N atoms (Cu-N 1.967(5)-2.029(5) A) of the tridentate ring-forming ligand HL and one Cl atom (Cu-Cl 2.281(2) angstrom). The coordination core CuN3Cl is a distorted square.
Cite:
Larionov S.V.
, Savel'eva Z.A.
, Glinskaya L.A.
, Klevtsova R.F.
, Ikorskii V.N.
, Bizyaev S.N.
, Tkachev A.V.
Synthesis and crystal and molecular structure of the complex [Cu(HL)Cl](2)[CuCl4], where HL is optically active terpenic (1S,3S,6R)-3-[N-(3-aminopropyl)aminol-4-caranone (E)-oxime
Russian Journal of Inorganic Chemistry. 2005. V.50. N5. P.711-714. WOS Scopus РИНЦ
Synthesis and crystal and molecular structure of the complex [Cu(HL)Cl](2)[CuCl4], where HL is optically active terpenic (1S,3S,6R)-3-[N-(3-aminopropyl)aminol-4-caranone (E)-oxime
Russian Journal of Inorganic Chemistry. 2005. V.50. N5. P.711-714. WOS Scopus РИНЦ
Original:
Ларионов С.В.
, Савельева З.А.
, Глинская Л.А.
, Клевцова Р.Ф.
, Икорский В.Н.
, Бизяев С.Н.
, Ткачев А.В.
СИНТЕЗ, КРИСТАЛЛИЧЕСКАЯ И МОЛЕКУЛЯРНАЯ СТРУКТУРА КОМПЛЕКСА [CU(HL)CL]2[CUCL4], ГДЕ HL - ОПТИЧЕСКИ АКТИВНЫЙ ТЕРПЕНОВЫЙ (E)-ОКСИМ (1S,3S,6R)-3-[N-(3-AМИНОПРОПИЛ)AМИНО]-4-КAPAНОНA)
Журнал неорганической химии. 2005. Т.50. №5. С.786-789. РИНЦ
СИНТЕЗ, КРИСТАЛЛИЧЕСКАЯ И МОЛЕКУЛЯРНАЯ СТРУКТУРА КОМПЛЕКСА [CU(HL)CL]2[CUCL4], ГДЕ HL - ОПТИЧЕСКИ АКТИВНЫЙ ТЕРПЕНОВЫЙ (E)-ОКСИМ (1S,3S,6R)-3-[N-(3-AМИНОПРОПИЛ)AМИНО]-4-КAPAНОНA)
Журнал неорганической химии. 2005. Т.50. №5. С.786-789. РИНЦ
Identifiers:
| Web of science: | WOS:000229354600012 |
| Scopus: | 2-s2.0-20444373011 |
| Elibrary: | 13497344 |