Synthesis and structure of optically active compounds [Ni(HL1)]NO3 and [Ni(HL2)]NO3 center dot H2O containing anions of diaminodioximes H2L1 and H2L2 derived from alpha-pinene and (+)-3-carene as ligands Full article
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284 |
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| Output data | Year: 2004, Volume: 30, Number: 12, Pages: 837-845 Pages count : 9 DOI: 10.1007/s11173-005-0018-1 | ||||
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Abstract:
New optically active levorotatory compounds [Ni(HL1)]NO3 (1) and [Ni(HL2)]NO3 (.) H2O (II) containine, the anions of chiral diaminodioximes, H2L1 and H2L2, derived from the terpenes alpha-pinene and (+)-3-carene, respectively, were synthesized. Complexes I and II were studied by X-ray diffraction. The crystal structures of compounds are ionic, being composed of the [Ni(HL1)](+) or [Ni(HL2)](+) cations and the outer-sphere NO3- anions. The Ni2+ ion coordinates four N atoms of the tetradentate chelating ligand, the NiN4 coordination unit being shaped like a tetrahedrally distorted square. Compounds I and 11 are diamagnetic, which corresponds to a low-spin d(8) configuration. The NMR spectra of compounds were recorded and analyzed.
Cite:
Larionov S.V.
, Myachina L.I.
, Savel'eva Z.A.
, Glinskaya L.A.
, Klevtsova R.F.
, Sheludyakova L.A.
, Tkachev A.V.
, Bizyaev S.N.
Synthesis and structure of optically active compounds [Ni(HL1)]NO3 and [Ni(HL2)]NO3 center dot H2O containing anions of diaminodioximes H2L1 and H2L2 derived from alpha-pinene and (+)-3-carene as ligands
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2004. V.30. N12. P.837-845. DOI: 10.1007/s11173-005-0018-1 WOS Scopus РИНЦ OpenAlex
Synthesis and structure of optically active compounds [Ni(HL1)]NO3 and [Ni(HL2)]NO3 center dot H2O containing anions of diaminodioximes H2L1 and H2L2 derived from alpha-pinene and (+)-3-carene as ligands
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2004. V.30. N12. P.837-845. DOI: 10.1007/s11173-005-0018-1 WOS Scopus РИНЦ OpenAlex
Original:
Ларионов С.В.
, Мячина Л.И.
, Савельева З.А.
, Глинская Л.А.
, Клевцова Р.Ф.
, Шелудякова Л.А.
, Ткачев А.В.
, Бизяев С.Н.
СИНТЕЗ И СТРУКТУРА ОПТИЧЕСКИ АКТИВНЫХ СОЕДИНЕНИЙ [NI(HL 1)]NO 3 И [NI(HL 2)]NO 3 · H 2O, СОДЕРЖАЩИХ ЛИГАНДЫ-АНИОНЫ ДИАМИНОДИОКСИМОВ H 2L 1, H 2L 2 - ПРОИЗВОДНЫХ α-ПИНЕНА И (+)-3-КАРЕНА
Координационная химия (RUSS J COORD CHEM+). 2004. Т.30. №12. С.888-896. РИНЦ
СИНТЕЗ И СТРУКТУРА ОПТИЧЕСКИ АКТИВНЫХ СОЕДИНЕНИЙ [NI(HL 1)]NO 3 И [NI(HL 2)]NO 3 · H 2O, СОДЕРЖАЩИХ ЛИГАНДЫ-АНИОНЫ ДИАМИНОДИОКСИМОВ H 2L 1, H 2L 2 - ПРОИЗВОДНЫХ α-ПИНЕНА И (+)-3-КАРЕНА
Координационная химия (RUSS J COORD CHEM+). 2004. Т.30. №12. С.888-896. РИНЦ
Dates:
| Published print: | Dec 1, 2004 |
Identifiers:
| Web of science: | WOS:000226009500002 |
| Scopus: | 2-s2.0-14944357381 |
| Elibrary: | 13453292 |
| OpenAlex: | W4233224521 |