Synthesis and structure of copper(II) complexes with diaminodioxime (H2L), a derivative of the monoterpenoid (+)-3-carene Full article
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284 |
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| Output data | Year: 2004, Volume: 30, Number: 12, Pages: 846-849 Pages count : 4 DOI: 10.1007/s11173-005-0022-5 | ||||
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Abstract:
Copper(II) compounds with the optically active diaminodioxime (H2L) derived from the monoterpenoid (+)-3-carene, Cu(H2L)(NO3)(2) (.) H2O (I), Cu(H2L)(ClO4)(2) (.) H2O (II), Cu(H2L)Br-2 (.) H2O (III), and Cu(H2L)SO4 (.) 0.5H(2)O (IV) with mu(eff) equal to 1.81, 1.79, 1.71, and 1.8 mu(B), respectively, were prepared. Studies of the complexes by IR and EPR spectroscopy showed that I and II are mononuclear ionic complexes. Compound III apparently has polymeric structure (the CuN4Br2 coordination unit). According to EPR data, the Cu2+ ions in polycrystalline compounds III and IV undergo exchange interactions.
Cite:
Larionov S.
, Myachina L.
, Sheludyakova L.
, Boguslavskii E.
, Tkachev A.
, Bizyaev S.
Synthesis and structure of copper(II) complexes with diaminodioxime (H2L), a derivative of the monoterpenoid (+)-3-carene
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2004. V.30. N12. P.846-849. DOI: 10.1007/s11173-005-0022-5 WOS Scopus РИНЦ OpenAlex
Synthesis and structure of copper(II) complexes with diaminodioxime (H2L), a derivative of the monoterpenoid (+)-3-carene
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2004. V.30. N12. P.846-849. DOI: 10.1007/s11173-005-0022-5 WOS Scopus РИНЦ OpenAlex
Original:
Ларионов С.В.
, Мячина Л.И.
, Шелудякова Л.А.
, Богуславский Е.Г.
, Ткачев А.В.
, Бизяев С.Н.
СИНТЕЗ И СТРОЕНИЕ КОМПЛЕКСОВ МЕДИ(II) С ДИАМИНОДИОКСИМОМ (H 2L) - ПРОИЗВОДНЫМ МОНОТЕРПЕНОИДА (+)-3-КАРЕНА
Координационная химия (RUSS J COORD CHEM+). 2004. Т.30. №12. С.897-900. РИНЦ
СИНТЕЗ И СТРОЕНИЕ КОМПЛЕКСОВ МЕДИ(II) С ДИАМИНОДИОКСИМОМ (H 2L) - ПРОИЗВОДНЫМ МОНОТЕРПЕНОИДА (+)-3-КАРЕНА
Координационная химия (RUSS J COORD CHEM+). 2004. Т.30. №12. С.897-900. РИНЦ
Dates:
| Published print: | Dec 1, 2004 |
Identifiers:
| Web of science: | WOS:000226009500003 |
| Scopus: | 2-s2.0-14944352277 |
| Elibrary: | 13465282 |
| OpenAlex: | W4252933707 |